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Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane. / Semitut, Evgeny Yu; Sukhikh, Taisiya S.; Filatov, Evgeny Yu et al.

In: Crystal Growth and Design, Vol. 17, No. 10, 04.10.2017, p. 5559-5567.

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Semitut EY, Sukhikh TS, Filatov EY, Anosova GA, Ryadun AA, Kovalenko KA et al. Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane. Crystal Growth and Design. 2017 Oct 4;17(10):5559-5567. doi: 10.1021/acs.cgd.7b01133

Author

Semitut, Evgeny Yu ; Sukhikh, Taisiya S. ; Filatov, Evgeny Yu et al. / Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane. In: Crystal Growth and Design. 2017 ; Vol. 17, No. 10. pp. 5559-5567.

BibTeX

@article{a363d424a258418481b0b24134a22558,
title = "Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane",
abstract = "Three new zinc three-dimensional coordination polymers with flexible 1, 3-bis(1, 2, 4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)] DMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3] DMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.",
keywords = "N-DONOR LIGANDS, COORDINATION POLYMERS, SEPARATION, COMPLEXES, TRANSFORMATIONS, ADSORPTION, FEATURES, DESIGN, SERIES, 2D",
author = "Semitut, {Evgeny Yu} and Sukhikh, {Taisiya S.} and Filatov, {Evgeny Yu} and Anosova, {Galina A.} and Ryadun, {Alexey A.} and Kovalenko, {Konstantin A.} and Potapov, {Andrei S.}",
year = "2017",
month = oct,
day = "4",
doi = "10.1021/acs.cgd.7b01133",
language = "English",
volume = "17",
pages = "5559--5567",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "10",

}

RIS

TY - JOUR

T1 - Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane

AU - Semitut, Evgeny Yu

AU - Sukhikh, Taisiya S.

AU - Filatov, Evgeny Yu

AU - Anosova, Galina A.

AU - Ryadun, Alexey A.

AU - Kovalenko, Konstantin A.

AU - Potapov, Andrei S.

PY - 2017/10/4

Y1 - 2017/10/4

N2 - Three new zinc three-dimensional coordination polymers with flexible 1, 3-bis(1, 2, 4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)] DMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3] DMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.

AB - Three new zinc three-dimensional coordination polymers with flexible 1, 3-bis(1, 2, 4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)] DMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3] DMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.

KW - N-DONOR LIGANDS

KW - COORDINATION POLYMERS

KW - SEPARATION

KW - COMPLEXES

KW - TRANSFORMATIONS

KW - ADSORPTION

KW - FEATURES

KW - DESIGN

KW - SERIES

KW - 2D

UR - http://www.scopus.com/inward/record.url?scp=85037729058&partnerID=8YFLogxK

U2 - 10.1021/acs.cgd.7b01133

DO - 10.1021/acs.cgd.7b01133

M3 - Article

AN - SCOPUS:85037729058

VL - 17

SP - 5559

EP - 5567

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 10

ER -

ID: 10063650