Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane. / Semitut, Evgeny Yu; Sukhikh, Taisiya S.; Filatov, Evgeny Yu и др.
в: Crystal Growth and Design, Том 17, № 10, 04.10.2017, стр. 5559-5567.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane
AU - Semitut, Evgeny Yu
AU - Sukhikh, Taisiya S.
AU - Filatov, Evgeny Yu
AU - Anosova, Galina A.
AU - Ryadun, Alexey A.
AU - Kovalenko, Konstantin A.
AU - Potapov, Andrei S.
PY - 2017/10/4
Y1 - 2017/10/4
N2 - Three new zinc three-dimensional coordination polymers with flexible 1, 3-bis(1, 2, 4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)] DMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3] DMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.
AB - Three new zinc three-dimensional coordination polymers with flexible 1, 3-bis(1, 2, 4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)] DMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3] DMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.
KW - N-DONOR LIGANDS
KW - COORDINATION POLYMERS
KW - SEPARATION
KW - COMPLEXES
KW - TRANSFORMATIONS
KW - ADSORPTION
KW - FEATURES
KW - DESIGN
KW - SERIES
KW - 2D
UR - http://www.scopus.com/inward/record.url?scp=85037729058&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.7b01133
DO - 10.1021/acs.cgd.7b01133
M3 - Article
AN - SCOPUS:85037729058
VL - 17
SP - 5559
EP - 5567
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 10
ER -
ID: 10063650