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Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine. / Baranov, Andrey Yu; Rakhmanova, Mariana I.; Samsonenko, Denis G. et al.

In: Inorganica Chimica Acta, Vol. 494, 01.08.2019, p. 78-83.

Research output: Contribution to journal › Article › peer-review

Harvard

Baranov, AY, Rakhmanova, MI, Samsonenko, DG, Malysheva, SF, Belogorlova, NA, Bagryanskaya, IY, Fedin, VP & Artem'ev, AV 2019, 'Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine', Inorganica Chimica Acta, vol. 494, pp. 78-83. https://doi.org/10.1016/j.ica.2019.05.015

APA

Baranov, A. Y., Rakhmanova, M. I., Samsonenko, D. G., Malysheva, S. F., Belogorlova, N. A., Bagryanskaya, I. Y., Fedin, V. P., & Artem'ev, A. V. (2019). Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine. Inorganica Chimica Acta, 494, 78-83. https://doi.org/10.1016/j.ica.2019.05.015

Vancouver

Baranov AY, Rakhmanova MI, Samsonenko DG, Malysheva SF, Belogorlova NA, Bagryanskaya IY et al. Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine. Inorganica Chimica Acta. 2019 Aug 1;494:78-83. doi: 10.1016/j.ica.2019.05.015

Author

Baranov, Andrey Yu ; Rakhmanova, Mariana I. ; Samsonenko, Denis G. et al. / Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine. In: Inorganica Chimica Acta. 2019 ; Vol. 494. pp. 78-83.

BibTeX

@article{19b1e2b14e554603bf9536791a729525,
title = "Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine",
abstract = "Coordination abilities of tris[2-(2-pyridyl)ethyl]phosphine (L) toward Ag(I) and Au(I) have been surveyed. Its reaction with AgClO4, AgNO3 and AgOTf results in self-assembly of 1D coordination polymers (CPs) of [Ag(L)X]n type (X = ClO4, NO3, OTf), built up by conjugated twelve-membered [Formula presented] cycles. The reaction of this phosphine with AgCl affords CP [Ag4Cl4(L)2]n, where in stepped cubane [Ag4Cl4] modules are bridged by “PyCH2CH2P” arms. Interaction of L with Au(tht)Cl produces linear [Au(L)Cl] complex, in which P-coordination is observed. CPs [Ag(L)ClO4]n and [Ag4Cl4(L)2]n at ambient temperature show pronounced excitation wavelength dependent photoluminescence originated by intraligand transitions.",
keywords = "Coordination polymers, Excitation wavelength dependent photoluminescence, Gold(I), Pyridylphosphines, Self-assembly, Silver(I), DESIGN, PHOSPHINE, CRYSTAL-STRUCTURE, SOLVENT, LIGANDS, LUMINESCENCE, SYSTEMATICS, COORDINATION POLYMERS, CLUSTER, EMISSION",
author = "Baranov, {Andrey Yu} and Rakhmanova, {Mariana I.} and Samsonenko, {Denis G.} and Malysheva, {Svetlana F.} and Belogorlova, {Nataliya A.} and Bagryanskaya, {Irina Yu} and Fedin, {Vladimir P.} and Artem'ev, {Alexander V.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",
year = "2019",
month = aug,
day = "1",
doi = "10.1016/j.ica.2019.05.015",
language = "English",
volume = "494",
pages = "78--83",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine

AU - Baranov, Andrey Yu

AU - Rakhmanova, Mariana I.

AU - Samsonenko, Denis G.

AU - Malysheva, Svetlana F.

AU - Belogorlova, Nataliya A.

AU - Bagryanskaya, Irina Yu

AU - Fedin, Vladimir P.

AU - Artem'ev, Alexander V.

N1 - Publisher Copyright: © 2019 Elsevier B.V.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - Coordination abilities of tris[2-(2-pyridyl)ethyl]phosphine (L) toward Ag(I) and Au(I) have been surveyed. Its reaction with AgClO4, AgNO3 and AgOTf results in self-assembly of 1D coordination polymers (CPs) of [Ag(L)X]n type (X = ClO4, NO3, OTf), built up by conjugated twelve-membered [Formula presented] cycles. The reaction of this phosphine with AgCl affords CP [Ag4Cl4(L)2]n, where in stepped cubane [Ag4Cl4] modules are bridged by “PyCH2CH2P” arms. Interaction of L with Au(tht)Cl produces linear [Au(L)Cl] complex, in which P-coordination is observed. CPs [Ag(L)ClO4]n and [Ag4Cl4(L)2]n at ambient temperature show pronounced excitation wavelength dependent photoluminescence originated by intraligand transitions.

AB - Coordination abilities of tris[2-(2-pyridyl)ethyl]phosphine (L) toward Ag(I) and Au(I) have been surveyed. Its reaction with AgClO4, AgNO3 and AgOTf results in self-assembly of 1D coordination polymers (CPs) of [Ag(L)X]n type (X = ClO4, NO3, OTf), built up by conjugated twelve-membered [Formula presented] cycles. The reaction of this phosphine with AgCl affords CP [Ag4Cl4(L)2]n, where in stepped cubane [Ag4Cl4] modules are bridged by “PyCH2CH2P” arms. Interaction of L with Au(tht)Cl produces linear [Au(L)Cl] complex, in which P-coordination is observed. CPs [Ag(L)ClO4]n and [Ag4Cl4(L)2]n at ambient temperature show pronounced excitation wavelength dependent photoluminescence originated by intraligand transitions.

KW - Coordination polymers

KW - Excitation wavelength dependent photoluminescence

KW - Gold(I)

KW - Pyridylphosphines

KW - Self-assembly

KW - Silver(I)

KW - DESIGN

KW - PHOSPHINE

KW - CRYSTAL-STRUCTURE

KW - SOLVENT

KW - LIGANDS

KW - LUMINESCENCE

KW - SYSTEMATICS

KW - COORDINATION POLYMERS

KW - CLUSTER

KW - EMISSION

UR - http://www.scopus.com/inward/record.url?scp=85066092031&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2019.05.015

DO - 10.1016/j.ica.2019.05.015

M3 - Article

AN - SCOPUS:85066092031

VL - 494

SP - 78

EP - 83

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 20161494