Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine. / Baranov, Andrey Yu; Rakhmanova, Mariana I.; Samsonenko, Denis G. и др.
в: Inorganica Chimica Acta, Том 494, 01.08.2019, стр. 78-83.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine
AU - Baranov, Andrey Yu
AU - Rakhmanova, Mariana I.
AU - Samsonenko, Denis G.
AU - Malysheva, Svetlana F.
AU - Belogorlova, Nataliya A.
AU - Bagryanskaya, Irina Yu
AU - Fedin, Vladimir P.
AU - Artem'ev, Alexander V.
N1 - Publisher Copyright: © 2019 Elsevier B.V.
PY - 2019/8/1
Y1 - 2019/8/1
N2 - Coordination abilities of tris[2-(2-pyridyl)ethyl]phosphine (L) toward Ag(I) and Au(I) have been surveyed. Its reaction with AgClO4, AgNO3 and AgOTf results in self-assembly of 1D coordination polymers (CPs) of [Ag(L)X]n type (X = ClO4, NO3, OTf), built up by conjugated twelve-membered [Formula presented] cycles. The reaction of this phosphine with AgCl affords CP [Ag4Cl4(L)2]n, where in stepped cubane [Ag4Cl4] modules are bridged by “PyCH2CH2P” arms. Interaction of L with Au(tht)Cl produces linear [Au(L)Cl] complex, in which P-coordination is observed. CPs [Ag(L)ClO4]n and [Ag4Cl4(L)2]n at ambient temperature show pronounced excitation wavelength dependent photoluminescence originated by intraligand transitions.
AB - Coordination abilities of tris[2-(2-pyridyl)ethyl]phosphine (L) toward Ag(I) and Au(I) have been surveyed. Its reaction with AgClO4, AgNO3 and AgOTf results in self-assembly of 1D coordination polymers (CPs) of [Ag(L)X]n type (X = ClO4, NO3, OTf), built up by conjugated twelve-membered [Formula presented] cycles. The reaction of this phosphine with AgCl affords CP [Ag4Cl4(L)2]n, where in stepped cubane [Ag4Cl4] modules are bridged by “PyCH2CH2P” arms. Interaction of L with Au(tht)Cl produces linear [Au(L)Cl] complex, in which P-coordination is observed. CPs [Ag(L)ClO4]n and [Ag4Cl4(L)2]n at ambient temperature show pronounced excitation wavelength dependent photoluminescence originated by intraligand transitions.
KW - Coordination polymers
KW - Excitation wavelength dependent photoluminescence
KW - Gold(I)
KW - Pyridylphosphines
KW - Self-assembly
KW - Silver(I)
KW - DESIGN
KW - PHOSPHINE
KW - CRYSTAL-STRUCTURE
KW - SOLVENT
KW - LIGANDS
KW - LUMINESCENCE
KW - SYSTEMATICS
KW - COORDINATION POLYMERS
KW - CLUSTER
KW - EMISSION
UR - http://www.scopus.com/inward/record.url?scp=85066092031&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2019.05.015
DO - 10.1016/j.ica.2019.05.015
M3 - Article
AN - SCOPUS:85066092031
VL - 494
SP - 78
EP - 83
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -
ID: 20161494