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Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands. / Mikhaylov, Maksim A.; Mironova, Alina D.; Brylev, Konstantin A. et al.

In: New Journal of Chemistry, Vol. 43, No. 41, 07.11.2019, p. 16338-16348.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhaylov, MA, Mironova, AD, Brylev, KA, Sukhikh, TS, Eltsov, IV, Stass, DV, Gushchin, AL, Kitamura, N & Sokolov, MN 2019, 'Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands', New Journal of Chemistry, vol. 43, no. 41, pp. 16338-16348. https://doi.org/10.1039/c9nj02971k

APA

Mikhaylov, M. A., Mironova, A. D., Brylev, K. A., Sukhikh, T. S., Eltsov, I. V., Stass, D. V., Gushchin, A. L., Kitamura, N., & Sokolov, M. N. (2019). Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands. New Journal of Chemistry, 43(41), 16338-16348. https://doi.org/10.1039/c9nj02971k

Vancouver

Mikhaylov MA, Mironova AD, Brylev KA, Sukhikh TS, Eltsov IV, Stass DV et al. Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands. New Journal of Chemistry. 2019 Nov 7;43(41):16338-16348. doi: 10.1039/c9nj02971k

Author

Mikhaylov, Maksim A. ; Mironova, Alina D. ; Brylev, Konstantin A. et al. / Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands. In: New Journal of Chemistry. 2019 ; Vol. 43, No. 41. pp. 16338-16348.

BibTeX

@article{ca36ffcd0a884ad8bafc150016a85448,
title = "Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands",
abstract = "Methylation of anionic cluster complexes [Re6Q8(CN)6]4- with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.",
keywords = "OCTAHEDRAL RHENIUM CLUSTER, PHOTOPHYSICAL PROPERTIES, LUMINESCENCE PROPERTIES, CHALCOGENIDE CLUSTERS, CRYSTAL-STRUCTURE, BUILDING-BLOCKS, EXCITED-STATE, COMPLEXES, REDOX, CORE",
author = "Mikhaylov, {Maksim A.} and Mironova, {Alina D.} and Brylev, {Konstantin A.} and Sukhikh, {Taisiya S.} and Eltsov, {Ilia V.} and Stass, {Dmitri V.} and Gushchin, {Artem L.} and Noboru Kitamura and Sokolov, {Maxim N.}",
note = "Publisher Copyright: This journal is {\textcopyright} 2019 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2019",
month = nov,
day = "7",
doi = "10.1039/c9nj02971k",
language = "English",
volume = "43",
pages = "16338--16348",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "41",

}

RIS

TY - JOUR

T1 - Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands

AU - Mikhaylov, Maksim A.

AU - Mironova, Alina D.

AU - Brylev, Konstantin A.

AU - Sukhikh, Taisiya S.

AU - Eltsov, Ilia V.

AU - Stass, Dmitri V.

AU - Gushchin, Artem L.

AU - Kitamura, Noboru

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: This journal is © 2019 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2019/11/7

Y1 - 2019/11/7

N2 - Methylation of anionic cluster complexes [Re6Q8(CN)6]4- with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.

AB - Methylation of anionic cluster complexes [Re6Q8(CN)6]4- with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.

KW - OCTAHEDRAL RHENIUM CLUSTER

KW - PHOTOPHYSICAL PROPERTIES

KW - LUMINESCENCE PROPERTIES

KW - CHALCOGENIDE CLUSTERS

KW - CRYSTAL-STRUCTURE

KW - BUILDING-BLOCKS

KW - EXCITED-STATE

KW - COMPLEXES

KW - REDOX

KW - CORE

UR - http://www.scopus.com/inward/record.url?scp=85074175614&partnerID=8YFLogxK

U2 - 10.1039/c9nj02971k

DO - 10.1039/c9nj02971k

M3 - Article

AN - SCOPUS:85074175614

VL - 43

SP - 16338

EP - 16348

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 41

ER -

ID: 21994359