Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands. / Mikhaylov, Maksim A.; Mironova, Alina D.; Brylev, Konstantin A. и др.
в: New Journal of Chemistry, Том 43, № 41, 07.11.2019, стр. 16338-16348.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands
AU - Mikhaylov, Maksim A.
AU - Mironova, Alina D.
AU - Brylev, Konstantin A.
AU - Sukhikh, Taisiya S.
AU - Eltsov, Ilia V.
AU - Stass, Dmitri V.
AU - Gushchin, Artem L.
AU - Kitamura, Noboru
AU - Sokolov, Maxim N.
N1 - Publisher Copyright: This journal is © 2019 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2019/11/7
Y1 - 2019/11/7
N2 - Methylation of anionic cluster complexes [Re6Q8(CN)6]4- with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.
AB - Methylation of anionic cluster complexes [Re6Q8(CN)6]4- with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.
KW - OCTAHEDRAL RHENIUM CLUSTER
KW - PHOTOPHYSICAL PROPERTIES
KW - LUMINESCENCE PROPERTIES
KW - CHALCOGENIDE CLUSTERS
KW - CRYSTAL-STRUCTURE
KW - BUILDING-BLOCKS
KW - EXCITED-STATE
KW - COMPLEXES
KW - REDOX
KW - CORE
UR - http://www.scopus.com/inward/record.url?scp=85074175614&partnerID=8YFLogxK
U2 - 10.1039/c9nj02971k
DO - 10.1039/c9nj02971k
M3 - Article
AN - SCOPUS:85074175614
VL - 43
SP - 16338
EP - 16348
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 41
ER -
ID: 21994359