Tetrafluorosubstituted Metal Phthalocyanines

Standard

Tetrafluorosubstituted Metal Phthalocyanines : Interplay between Saturated Vapor Pressure and Crystal Structure. / Klyamer, Darya D.; Sukhikh, Aleksander S.; Trubin, Sergey V. et al.

In: Crystal Growth and Design, Vol. 20, No. 2, 05.02.2020, p. 1016-1024.

Research output: Contribution to journal › Article › peer-review

Harvard

Klyamer, DD, Sukhikh, AS, Trubin, SV, Gromilov, SA, Morozova, NB, Basova, TV & Hassan, AK 2020, 'Tetrafluorosubstituted Metal Phthalocyanines: Interplay between Saturated Vapor Pressure and Crystal Structure', Crystal Growth and Design, vol. 20, no. 2, pp. 1016-1024. https://doi.org/10.1021/acs.cgd.9b01350

APA

Klyamer, D. D., Sukhikh, A. S., Trubin, S. V., Gromilov, S. A., Morozova, N. B., Basova, T. V., & Hassan, A. K. (2020). Tetrafluorosubstituted Metal Phthalocyanines: Interplay between Saturated Vapor Pressure and Crystal Structure. Crystal Growth and Design, 20(2), 1016-1024. https://doi.org/10.1021/acs.cgd.9b01350

Vancouver

Klyamer DD, Sukhikh AS, Trubin SV, Gromilov SA, Morozova NB, Basova TV et al. Tetrafluorosubstituted Metal Phthalocyanines: Interplay between Saturated Vapor Pressure and Crystal Structure. Crystal Growth and Design. 2020 Feb 5;20(2):1016-1024. doi: 10.1021/acs.cgd.9b01350

Author

Klyamer, Darya D. ; Sukhikh, Aleksander S. ; Trubin, Sergey V. et al. / Tetrafluorosubstituted Metal Phthalocyanines : Interplay between Saturated Vapor Pressure and Crystal Structure. In: Crystal Growth and Design. 2020 ; Vol. 20, No. 2. pp. 1016-1024.

BibTeX

@article{dbc9c2bfa8634849995f5a71dfa092de,

title = "Tetrafluorosubstituted Metal Phthalocyanines: Interplay between Saturated Vapor Pressure and Crystal Structure",

abstract = "In this work, we study the effect of fluorosubstitution on the crystal structure of phthalocyanines of copper, cobalt, and vanadyl and analyze the correlations between the structure and volatility of these complexes. The structures of MPcF4 (M = Cu, Co, VO) single crystals were refined; their vapor pressure was determined as a function of temperature by the Knudsen effusion method and the standard thermodynamic parameters ΔHT and ΔST0 of the sublimation process were determined. These characteristics were compared with those of unsubstituted MPc and hexadecafluorosubstituted derivatives. Hirshfeld surface analysis was used as a powerful tool for the visualization and better insight into intermolecular contacts in these molecular structures.",

keywords = "THIN-FILMS, COBALT PHTHALOCYANINE, FLUOROSUBSTITUTION, THERMODYNAMICS, CHEMISTRY, ALPHA, GAS",

author = "Klyamer, {Darya D.} and Sukhikh, {Aleksander S.} and Trubin, {Sergey V.} and Gromilov, {Sergey A.} and Morozova, {Natalia B.} and Basova, {Tamara V.} and Hassan, {Aseel K.}",

year = "2020",

month = feb,

day = "5",

doi = "10.1021/acs.cgd.9b01350",

language = "English",

volume = "20",

pages = "1016--1024",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "2",

}

RIS

TY - JOUR

T1 - Tetrafluorosubstituted Metal Phthalocyanines

T2 - Interplay between Saturated Vapor Pressure and Crystal Structure

AU - Klyamer, Darya D.

AU - Sukhikh, Aleksander S.

AU - Trubin, Sergey V.

AU - Gromilov, Sergey A.

AU - Morozova, Natalia B.

AU - Basova, Tamara V.

AU - Hassan, Aseel K.

PY - 2020/2/5

Y1 - 2020/2/5

N2 - In this work, we study the effect of fluorosubstitution on the crystal structure of phthalocyanines of copper, cobalt, and vanadyl and analyze the correlations between the structure and volatility of these complexes. The structures of MPcF4 (M = Cu, Co, VO) single crystals were refined; their vapor pressure was determined as a function of temperature by the Knudsen effusion method and the standard thermodynamic parameters ΔHT and ΔST0 of the sublimation process were determined. These characteristics were compared with those of unsubstituted MPc and hexadecafluorosubstituted derivatives. Hirshfeld surface analysis was used as a powerful tool for the visualization and better insight into intermolecular contacts in these molecular structures.

AB - In this work, we study the effect of fluorosubstitution on the crystal structure of phthalocyanines of copper, cobalt, and vanadyl and analyze the correlations between the structure and volatility of these complexes. The structures of MPcF4 (M = Cu, Co, VO) single crystals were refined; their vapor pressure was determined as a function of temperature by the Knudsen effusion method and the standard thermodynamic parameters ΔHT and ΔST0 of the sublimation process were determined. These characteristics were compared with those of unsubstituted MPc and hexadecafluorosubstituted derivatives. Hirshfeld surface analysis was used as a powerful tool for the visualization and better insight into intermolecular contacts in these molecular structures.

KW - THIN-FILMS

KW - COBALT PHTHALOCYANINE

KW - FLUOROSUBSTITUTION

KW - THERMODYNAMICS

KW - CHEMISTRY

KW - ALPHA

KW - GAS

UR - http://www.scopus.com/inward/record.url?scp=85079676770&partnerID=8YFLogxK

U2 - 10.1021/acs.cgd.9b01350

DO - 10.1021/acs.cgd.9b01350

M3 - Article

AN - SCOPUS:85079676770

VL - 20

SP - 1016

EP - 1024

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 2

ER -

ID: 23594480