Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Tetrafluorosubstituted Metal Phthalocyanines : Interplay between Saturated Vapor Pressure and Crystal Structure. / Klyamer, Darya D.; Sukhikh, Aleksander S.; Trubin, Sergey V. и др.
в: Crystal Growth and Design, Том 20, № 2, 05.02.2020, стр. 1016-1024.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Tetrafluorosubstituted Metal Phthalocyanines
T2 - Interplay between Saturated Vapor Pressure and Crystal Structure
AU - Klyamer, Darya D.
AU - Sukhikh, Aleksander S.
AU - Trubin, Sergey V.
AU - Gromilov, Sergey A.
AU - Morozova, Natalia B.
AU - Basova, Tamara V.
AU - Hassan, Aseel K.
N1 - Publisher Copyright: © 2020 American Chemical Society. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/2/5
Y1 - 2020/2/5
N2 - In this work, we study the effect of fluorosubstitution on the crystal structure of phthalocyanines of copper, cobalt, and vanadyl and analyze the correlations between the structure and volatility of these complexes. The structures of MPcF4 (M = Cu, Co, VO) single crystals were refined; their vapor pressure was determined as a function of temperature by the Knudsen effusion method and the standard thermodynamic parameters ΔHT and ΔST0 of the sublimation process were determined. These characteristics were compared with those of unsubstituted MPc and hexadecafluorosubstituted derivatives. Hirshfeld surface analysis was used as a powerful tool for the visualization and better insight into intermolecular contacts in these molecular structures.
AB - In this work, we study the effect of fluorosubstitution on the crystal structure of phthalocyanines of copper, cobalt, and vanadyl and analyze the correlations between the structure and volatility of these complexes. The structures of MPcF4 (M = Cu, Co, VO) single crystals were refined; their vapor pressure was determined as a function of temperature by the Knudsen effusion method and the standard thermodynamic parameters ΔHT and ΔST0 of the sublimation process were determined. These characteristics were compared with those of unsubstituted MPc and hexadecafluorosubstituted derivatives. Hirshfeld surface analysis was used as a powerful tool for the visualization and better insight into intermolecular contacts in these molecular structures.
KW - THIN-FILMS
KW - COBALT PHTHALOCYANINE
KW - FLUOROSUBSTITUTION
KW - THERMODYNAMICS
KW - CHEMISTRY
KW - ALPHA
KW - GAS
UR - http://www.scopus.com/inward/record.url?scp=85079676770&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.9b01350
DO - 10.1021/acs.cgd.9b01350
M3 - Article
AN - SCOPUS:85079676770
VL - 20
SP - 1016
EP - 1024
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 2
ER -
ID: 23594480