Standard

Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores. / Petrov, Pavel A.; Naumov, Dmitry Yu; Sukhikh, Taisiya S. et al.

In: New Journal of Chemistry, Vol. 41, No. 16, 21.08.2017, p. 7849-7852.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Naumov, DY, Sukhikh, TS, Konchenko, SN, Gómez-García, CJ & Llusar, R 2017, 'Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores', New Journal of Chemistry, vol. 41, no. 16, pp. 7849-7852. https://doi.org/10.1039/c7nj01217a

APA

Petrov, P. A., Naumov, D. Y., Sukhikh, T. S., Konchenko, S. N., Gómez-García, C. J., & Llusar, R. (2017). Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores. New Journal of Chemistry, 41(16), 7849-7852. https://doi.org/10.1039/c7nj01217a

Vancouver

Petrov PA, Naumov DY, Sukhikh TS, Konchenko SN, Gómez-García CJ, Llusar R. Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores. New Journal of Chemistry. 2017 Aug 21;41(16):7849-7852. doi: 10.1039/c7nj01217a

Author

Petrov, Pavel A. ; Naumov, Dmitry Yu ; Sukhikh, Taisiya S. et al. / Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores. In: New Journal of Chemistry. 2017 ; Vol. 41, No. 16. pp. 7849-7852.

BibTeX

@article{9e70db0ecd994e0c88f124f2bc5a52ff,
title = "Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores",
abstract = "Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.",
keywords = "X-RAY-STRUCTURE, MIXED-METAL CLUSTER, SHARED DOUBLE CUBE, MOLYBDENUM, COMPLEXES, DERIVATIVES, REACTIVITY, SINGLE, MO",
author = "Petrov, {Pavel A.} and Naumov, {Dmitry Yu} and Sukhikh, {Taisiya S.} and Konchenko, {Sergey N.} and G{\'o}mez-Garc{\'i}a, {Carlos J.} and Rosa Llusar",
year = "2017",
month = aug,
day = "21",
doi = "10.1039/c7nj01217a",
language = "English",
volume = "41",
pages = "7849--7852",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "16",

}

RIS

TY - JOUR

T1 - Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

AU - Petrov, Pavel A.

AU - Naumov, Dmitry Yu

AU - Sukhikh, Taisiya S.

AU - Konchenko, Sergey N.

AU - Gómez-García, Carlos J.

AU - Llusar, Rosa

PY - 2017/8/21

Y1 - 2017/8/21

N2 - Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

AB - Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

KW - X-RAY-STRUCTURE

KW - MIXED-METAL CLUSTER

KW - SHARED DOUBLE CUBE

KW - MOLYBDENUM

KW - COMPLEXES

KW - DERIVATIVES

KW - REACTIVITY

KW - SINGLE

KW - MO

UR - http://www.scopus.com/inward/record.url?scp=85027040811&partnerID=8YFLogxK

U2 - 10.1039/c7nj01217a

DO - 10.1039/c7nj01217a

M3 - Article

AN - SCOPUS:85027040811

VL - 41

SP - 7849

EP - 7852

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 16

ER -

ID: 9966924