Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores. / Petrov, Pavel A.; Naumov, Dmitry Yu; Sukhikh, Taisiya S. и др.
в: New Journal of Chemistry, Том 41, № 16, 21.08.2017, стр. 7849-7852.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores
AU - Petrov, Pavel A.
AU - Naumov, Dmitry Yu
AU - Sukhikh, Taisiya S.
AU - Konchenko, Sergey N.
AU - Gómez-García, Carlos J.
AU - Llusar, Rosa
PY - 2017/8/21
Y1 - 2017/8/21
N2 - Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.
AB - Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.
KW - X-RAY-STRUCTURE
KW - MIXED-METAL CLUSTER
KW - SHARED DOUBLE CUBE
KW - MOLYBDENUM
KW - COMPLEXES
KW - DERIVATIVES
KW - REACTIVITY
KW - SINGLE
KW - MO
UR - http://www.scopus.com/inward/record.url?scp=85027040811&partnerID=8YFLogxK
U2 - 10.1039/c7nj01217a
DO - 10.1039/c7nj01217a
M3 - Article
AN - SCOPUS:85027040811
VL - 41
SP - 7849
EP - 7852
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 16
ER -
ID: 9966924