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Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core. / Mikhailov, M. A.; Virovets, A. V.; Peresypkina, E. V. et al.

In: Journal of Structural Chemistry, Vol. 59, No. 1, 01.01.2018, p. 177-181.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhailov, MA, Virovets, AV, Peresypkina, EV, Brylev, KA & Sokolov, MN 2018, 'Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core', Journal of Structural Chemistry, vol. 59, no. 1, pp. 177-181. https://doi.org/10.1134/S0022476618010274

APA

Mikhailov, M. A., Virovets, A. V., Peresypkina, E. V., Brylev, K. A., & Sokolov, M. N. (2018). Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core. Journal of Structural Chemistry, 59(1), 177-181. https://doi.org/10.1134/S0022476618010274

Vancouver

Mikhailov MA, Virovets AV, Peresypkina EV, Brylev KA, Sokolov MN. Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core. Journal of Structural Chemistry. 2018 Jan 1;59(1):177-181. doi: 10.1134/S0022476618010274

Author

Mikhailov, M. A. ; Virovets, A. V. ; Peresypkina, E. V. et al. / Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 1. pp. 177-181.

BibTeX

@article{7c315f8bc91e4901b4a010a7bf934cdf,
title = "Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core",
abstract = "The selenium atom substitution for one of the capping chloride ligands in [Mo6(μ3-Cl8)Cl6]2– under the action of H2Se in situ results in a [Mo6(μ3-SeCl7)Cl6]3– cluster which is isolated and structurally characterized in the form of (Bu4N)3[Mo6(μ3-SeCl7)Cl6] (I). In the acetonitrile solution the complex exhibits luminescence (λmax = 775 nm, τem = 1.8 μs, Φem = 0.004). When the solution of I in acetonitrile is heated, a partial solvolysis product of the composition (Bu4N)2[Mo6(μ3-SeCl7)Cl5(CH3CN)] (II) is isolated and structurally characterized.",
keywords = "crystal structure, luminescence, molybdenum cluster complexes, solvation, substitution of bridging chloride ligands, synthesis",
author = "Mikhailov, {M. A.} and Virovets, {A. V.} and Peresypkina, {E. V.} and Brylev, {K. A.} and Sokolov, {M. N.}",
year = "2018",
month = jan,
day = "1",
doi = "10.1134/S0022476618010274",
language = "English",
volume = "59",
pages = "177--181",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

RIS

TY - JOUR

T1 - Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core

AU - Mikhailov, M. A.

AU - Virovets, A. V.

AU - Peresypkina, E. V.

AU - Brylev, K. A.

AU - Sokolov, M. N.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The selenium atom substitution for one of the capping chloride ligands in [Mo6(μ3-Cl8)Cl6]2– under the action of H2Se in situ results in a [Mo6(μ3-SeCl7)Cl6]3– cluster which is isolated and structurally characterized in the form of (Bu4N)3[Mo6(μ3-SeCl7)Cl6] (I). In the acetonitrile solution the complex exhibits luminescence (λmax = 775 nm, τem = 1.8 μs, Φem = 0.004). When the solution of I in acetonitrile is heated, a partial solvolysis product of the composition (Bu4N)2[Mo6(μ3-SeCl7)Cl5(CH3CN)] (II) is isolated and structurally characterized.

AB - The selenium atom substitution for one of the capping chloride ligands in [Mo6(μ3-Cl8)Cl6]2– under the action of H2Se in situ results in a [Mo6(μ3-SeCl7)Cl6]3– cluster which is isolated and structurally characterized in the form of (Bu4N)3[Mo6(μ3-SeCl7)Cl6] (I). In the acetonitrile solution the complex exhibits luminescence (λmax = 775 nm, τem = 1.8 μs, Φem = 0.004). When the solution of I in acetonitrile is heated, a partial solvolysis product of the composition (Bu4N)2[Mo6(μ3-SeCl7)Cl5(CH3CN)] (II) is isolated and structurally characterized.

KW - crystal structure

KW - luminescence

KW - molybdenum cluster complexes

KW - solvation

KW - substitution of bridging chloride ligands

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=85044054353&partnerID=8YFLogxK

U2 - 10.1134/S0022476618010274

DO - 10.1134/S0022476618010274

M3 - Article

AN - SCOPUS:85044054353

VL - 59

SP - 177

EP - 181

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 12155069