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Phosphorescent complexes of {Mo6I8}4+with triazolates : [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-. / Mironova, Alina D.; Mikhailov, Maksim A.; Brylev, Konstantin A. et al.

In: New Journal of Chemistry, Vol. 44, No. 47, 21.12.2020, p. 20620-20625.

Research output: Contribution to journal › Article › peer-review

Harvard

Mironova, AD, Mikhailov, MA, Brylev, KA, Gushchin, AL, Sukhikh, TS & Sokolov, MN 2020, 'Phosphorescent complexes of {Mo6I8}4+with triazolates: [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-', New Journal of Chemistry, vol. 44, no. 47, pp. 20620-20625. https://doi.org/10.1039/d0nj04259e

APA

Mironova, A. D., Mikhailov, M. A., Brylev, K. A., Gushchin, A. L., Sukhikh, T. S., & Sokolov, M. N. (2020). Phosphorescent complexes of {Mo6I8}4+with triazolates: [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-. New Journal of Chemistry, 44(47), 20620-20625. https://doi.org/10.1039/d0nj04259e

Vancouver

Mironova AD, Mikhailov MA, Brylev KA, Gushchin AL, Sukhikh TS, Sokolov MN. Phosphorescent complexes of {Mo6I8}4+with triazolates: [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-. New Journal of Chemistry. 2020 Dec 21;44(47):20620-20625. doi: 10.1039/d0nj04259e

Author

Mironova, Alina D. ; Mikhailov, Maksim A. ; Brylev, Konstantin A. et al. / Phosphorescent complexes of {Mo6I8}4+with triazolates : [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-. In: New Journal of Chemistry. 2020 ; Vol. 44, No. 47. pp. 20620-20625.

BibTeX

@article{947c8ef0bc2b4df38f0f8b88e92cb56b,
title = "Phosphorescent complexes of {Mo6I8}4+with triazolates: [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-",
abstract = "(Bu4N)2[Mo6I8(N3)6], prepared in a clean high-yield reaction from (Bu4N)2[Mo6I8(CH3COO)6] and Me3SiN3, undergoes [3+2] cycloaddition with CH3O(O)CC(O)OCH3 with the formation of a novel hexakis(triazolate) complex, (Bu4N)2[Mo6I8(N3C2(COOCH3)2)6] with symmetrically coordinated 4,5-di(carbmethoxy)triazol-2-yl ligands. The product was characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. It undergoes a quasi reversible oxidation in CH3CN at E1/2 = 1.36 V (vs. Ag/AgCl) and is red-light emissive upon UV photoexcitation. Reaction with methylpropiolate also yields a corresponding hexakis(triazolate) complex, [Mo6I8(N3C2H(COOCH3))6]2-, which exists as a 1:1 mixture of two isomers. Alkynes that lacking strongly electron-withdrawing substituents fail to undergo the cycloaddition reaction. This journal is ",
keywords = "RHENIUM CLUSTER COMPLEXES, OCTAHEDRAL HEXARHENIUM(III) COMPLEXES, EXCITED-STATE PROPERTIES, HEXANUCLEAR MOLYBDENUM, SUPRAMOLECULAR ASSEMBLIES, PHOTOPHYSICAL PROPERTIES, IODIDE CLUSTER, LUMINESCENCE, AZIDES, REDOX",
author = "Mironova, {Alina D.} and Mikhailov, {Maksim A.} and Brylev, {Konstantin A.} and Gushchin, {Artem L.} and Sukhikh, {Taisiya S.} and Sokolov, {Maxim N.}",
note = "Funding Information: ADM, MAM and KAB thank the Russian Science Foundation (grant no. 19-73-20196) for the financial support. Some experimental measurements were performed in the Center for Optical and Laser materials research (St. Petersburg State University, St. Petersburg, Russian Federation). Financial support from RFBR (20-03-00410) for the synthetic work is gratefully acknowledged. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = dec,
day = "21",
doi = "10.1039/d0nj04259e",
language = "English",
volume = "44",
pages = "20620--20625",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "47",

}

RIS

TY - JOUR

T1 - Phosphorescent complexes of {Mo6I8}4+with triazolates

T2 - [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-

AU - Mironova, Alina D.

AU - Mikhailov, Maksim A.

AU - Brylev, Konstantin A.

AU - Gushchin, Artem L.

AU - Sukhikh, Taisiya S.

AU - Sokolov, Maxim N.

N1 - Funding Information: ADM, MAM and KAB thank the Russian Science Foundation (grant no. 19-73-20196) for the financial support. Some experimental measurements were performed in the Center for Optical and Laser materials research (St. Petersburg State University, St. Petersburg, Russian Federation). Financial support from RFBR (20-03-00410) for the synthetic work is gratefully acknowledged. Publisher Copyright: © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/12/21

Y1 - 2020/12/21

N2 - (Bu4N)2[Mo6I8(N3)6], prepared in a clean high-yield reaction from (Bu4N)2[Mo6I8(CH3COO)6] and Me3SiN3, undergoes [3+2] cycloaddition with CH3O(O)CC(O)OCH3 with the formation of a novel hexakis(triazolate) complex, (Bu4N)2[Mo6I8(N3C2(COOCH3)2)6] with symmetrically coordinated 4,5-di(carbmethoxy)triazol-2-yl ligands. The product was characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. It undergoes a quasi reversible oxidation in CH3CN at E1/2 = 1.36 V (vs. Ag/AgCl) and is red-light emissive upon UV photoexcitation. Reaction with methylpropiolate also yields a corresponding hexakis(triazolate) complex, [Mo6I8(N3C2H(COOCH3))6]2-, which exists as a 1:1 mixture of two isomers. Alkynes that lacking strongly electron-withdrawing substituents fail to undergo the cycloaddition reaction. This journal is

AB - (Bu4N)2[Mo6I8(N3)6], prepared in a clean high-yield reaction from (Bu4N)2[Mo6I8(CH3COO)6] and Me3SiN3, undergoes [3+2] cycloaddition with CH3O(O)CC(O)OCH3 with the formation of a novel hexakis(triazolate) complex, (Bu4N)2[Mo6I8(N3C2(COOCH3)2)6] with symmetrically coordinated 4,5-di(carbmethoxy)triazol-2-yl ligands. The product was characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. It undergoes a quasi reversible oxidation in CH3CN at E1/2 = 1.36 V (vs. Ag/AgCl) and is red-light emissive upon UV photoexcitation. Reaction with methylpropiolate also yields a corresponding hexakis(triazolate) complex, [Mo6I8(N3C2H(COOCH3))6]2-, which exists as a 1:1 mixture of two isomers. Alkynes that lacking strongly electron-withdrawing substituents fail to undergo the cycloaddition reaction. This journal is

KW - RHENIUM CLUSTER COMPLEXES

KW - OCTAHEDRAL HEXARHENIUM(III) COMPLEXES

KW - EXCITED-STATE PROPERTIES

KW - HEXANUCLEAR MOLYBDENUM

KW - SUPRAMOLECULAR ASSEMBLIES

KW - PHOTOPHYSICAL PROPERTIES

KW - IODIDE CLUSTER

KW - LUMINESCENCE

KW - AZIDES

KW - REDOX

UR - http://www.scopus.com/inward/record.url?scp=85098084770&partnerID=8YFLogxK

U2 - 10.1039/d0nj04259e

DO - 10.1039/d0nj04259e

M3 - Article

AN - SCOPUS:85098084770

VL - 44

SP - 20620

EP - 20625

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 47

ER -

ID: 27331759