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Mixed-metal clusters with a {Re3Mo3Se8} core : From a polymeric solid to soluble species with multiple redox transitions. / Muravieva, Viktoria K.; Gayfulin, Yakov M.; Ryzhikov, Maxim R. et al.

In: Dalton Transactions, Vol. 47, No. 10, 14.03.2018, p. 3366-3377.

Research output: Contribution to journal › Article › peer-review

Harvard

Muravieva, VK, Gayfulin, YM, Ryzhikov, MR, Novozhilov, IN, Samsonenko, DG, Piryazev, DA, Yanshole, VV & Naumov, NG 2018, 'Mixed-metal clusters with a {Re3Mo3Se8} core: From a polymeric solid to soluble species with multiple redox transitions', Dalton Transactions, vol. 47, no. 10, pp. 3366-3377. https://doi.org/10.1039/c7dt03571c

APA

Muravieva, V. K., Gayfulin, Y. M., Ryzhikov, M. R., Novozhilov, I. N., Samsonenko, D. G., Piryazev, D. A., Yanshole, V. V., & Naumov, N. G. (2018). Mixed-metal clusters with a {Re3Mo3Se8} core: From a polymeric solid to soluble species with multiple redox transitions. Dalton Transactions, 47(10), 3366-3377. https://doi.org/10.1039/c7dt03571c

Vancouver

Muravieva VK, Gayfulin YM, Ryzhikov MR, Novozhilov IN, Samsonenko DG, Piryazev DA et al. Mixed-metal clusters with a {Re3Mo3Se8} core: From a polymeric solid to soluble species with multiple redox transitions. Dalton Transactions. 2018 Mar 14;47(10):3366-3377. doi: 10.1039/c7dt03571c

Author

Muravieva, Viktoria K. ; Gayfulin, Yakov M. ; Ryzhikov, Maxim R. et al. / Mixed-metal clusters with a {Re3Mo3Se8} core : From a polymeric solid to soluble species with multiple redox transitions. In: Dalton Transactions. 2018 ; Vol. 47, No. 10. pp. 3366-3377.

BibTeX

@article{69d183b74ad3457bab616c82f5720539,
title = "Mixed-metal clusters with a {Re3Mo3Se8} core: From a polymeric solid to soluble species with multiple redox transitions",
abstract = "Cluster compounds based on a new {Re3Mo3Se8}n core were obtained and studied. The polymeric solid K6[Re3Mo3Se8(CN)4(CN)2/2] (1) containing 24 cluster valence electrons (CVE) was isolated as a result of high-temperature reaction. Water-soluble salts K5[Re3Mo3Se8(CN)6]·11H2O (2) and Cs5[Re3Mo3Se8(CN)6]·H2O (3) were prepared from compound 1. Crystal structures of the diamagnetic compounds 2 and 3 contain a cluster anion [Re3Mo3Se8(CN)6]5- with a 22-electronic core {Re3Mo3Se8}+. Metathesis reaction followed by recrystallization from CH3CN yielded paramagnetic salt (Ph4P)4[Re3Mo3Se8(CN)6]·2CH3CN (4) containing the {Re3Mo3Se8}2+ core with 21 CVE. Cyclic voltammetry of the solution of 4 displayed three quasi-reversible waves with E1/2 = -0.325, -0.818 and -1.410 V vs. Ag/AgCl electrode indicating the presence of [Re3Mo3Se8(CN)6]4-/5-/6-/7- transitions. Electronic structure calculations showed that both mer- and fac-isomers of [Re3Mo3Se8(CN)6]n- clusters undergo great distortion when the number of CVE decreases.",
keywords = "RHENIUM CLUSTER, PRUSSIAN BLUE, ELECTRONIC-STRUCTURE, OCTAHEDRAL CLUSTERS, MOLYBDENUM CLUSTER, CRYSTAL-STRUCTURES, HEXANUCLEAR, LUMINESCENT, SE, COMPLEXES",
author = "Muravieva, {Viktoria K.} and Gayfulin, {Yakov M.} and Ryzhikov, {Maxim R.} and Novozhilov, {Igor N.} and Samsonenko, {Denis G.} and Piryazev, {Dmitry A.} and Yanshole, {Vadim V.} and Naumov, {Nikolay G.}",
year = "2018",
month = mar,
day = "14",
doi = "10.1039/c7dt03571c",
language = "English",
volume = "47",
pages = "3366--3377",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "10",

}

RIS

TY - JOUR

T1 - Mixed-metal clusters with a {Re3Mo3Se8} core

T2 - From a polymeric solid to soluble species with multiple redox transitions

AU - Muravieva, Viktoria K.

AU - Gayfulin, Yakov M.

AU - Ryzhikov, Maxim R.

AU - Novozhilov, Igor N.

AU - Samsonenko, Denis G.

AU - Piryazev, Dmitry A.

AU - Yanshole, Vadim V.

AU - Naumov, Nikolay G.

PY - 2018/3/14

Y1 - 2018/3/14

N2 - Cluster compounds based on a new {Re3Mo3Se8}n core were obtained and studied. The polymeric solid K6[Re3Mo3Se8(CN)4(CN)2/2] (1) containing 24 cluster valence electrons (CVE) was isolated as a result of high-temperature reaction. Water-soluble salts K5[Re3Mo3Se8(CN)6]·11H2O (2) and Cs5[Re3Mo3Se8(CN)6]·H2O (3) were prepared from compound 1. Crystal structures of the diamagnetic compounds 2 and 3 contain a cluster anion [Re3Mo3Se8(CN)6]5- with a 22-electronic core {Re3Mo3Se8}+. Metathesis reaction followed by recrystallization from CH3CN yielded paramagnetic salt (Ph4P)4[Re3Mo3Se8(CN)6]·2CH3CN (4) containing the {Re3Mo3Se8}2+ core with 21 CVE. Cyclic voltammetry of the solution of 4 displayed three quasi-reversible waves with E1/2 = -0.325, -0.818 and -1.410 V vs. Ag/AgCl electrode indicating the presence of [Re3Mo3Se8(CN)6]4-/5-/6-/7- transitions. Electronic structure calculations showed that both mer- and fac-isomers of [Re3Mo3Se8(CN)6]n- clusters undergo great distortion when the number of CVE decreases.

AB - Cluster compounds based on a new {Re3Mo3Se8}n core were obtained and studied. The polymeric solid K6[Re3Mo3Se8(CN)4(CN)2/2] (1) containing 24 cluster valence electrons (CVE) was isolated as a result of high-temperature reaction. Water-soluble salts K5[Re3Mo3Se8(CN)6]·11H2O (2) and Cs5[Re3Mo3Se8(CN)6]·H2O (3) were prepared from compound 1. Crystal structures of the diamagnetic compounds 2 and 3 contain a cluster anion [Re3Mo3Se8(CN)6]5- with a 22-electronic core {Re3Mo3Se8}+. Metathesis reaction followed by recrystallization from CH3CN yielded paramagnetic salt (Ph4P)4[Re3Mo3Se8(CN)6]·2CH3CN (4) containing the {Re3Mo3Se8}2+ core with 21 CVE. Cyclic voltammetry of the solution of 4 displayed three quasi-reversible waves with E1/2 = -0.325, -0.818 and -1.410 V vs. Ag/AgCl electrode indicating the presence of [Re3Mo3Se8(CN)6]4-/5-/6-/7- transitions. Electronic structure calculations showed that both mer- and fac-isomers of [Re3Mo3Se8(CN)6]n- clusters undergo great distortion when the number of CVE decreases.

KW - RHENIUM CLUSTER

KW - PRUSSIAN BLUE

KW - ELECTRONIC-STRUCTURE

KW - OCTAHEDRAL CLUSTERS

KW - MOLYBDENUM CLUSTER

KW - CRYSTAL-STRUCTURES

KW - HEXANUCLEAR

KW - LUMINESCENT

KW - SE

KW - COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85043352220&partnerID=8YFLogxK

U2 - 10.1039/c7dt03571c

DO - 10.1039/c7dt03571c

M3 - Article

C2 - 29423497

AN - SCOPUS:85043352220

VL - 47

SP - 3366

EP - 3377

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 10

ER -

ID: 10422687