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Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers. / Litvinova, Y. M.; Gayfulin, Y. M.; Samsonenko, D. G. et al.

In: Russian Chemical Bulletin, Vol. 69, No. 7, 01.07.2020, p. 1264-1271.

Research output: Contribution to journal › Article › peer-review

Harvard

Litvinova, YM, Gayfulin, YM, Samsonenko, DG & Mironov, YV 2020, 'Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers', Russian Chemical Bulletin, vol. 69, no. 7, pp. 1264-1271. https://doi.org/10.1007/s11172-020-2896-2

APA

Litvinova, Y. M., Gayfulin, Y. M., Samsonenko, D. G., & Mironov, Y. V. (2020). Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers. Russian Chemical Bulletin, 69(7), 1264-1271. https://doi.org/10.1007/s11172-020-2896-2

Vancouver

Litvinova YM, Gayfulin YM, Samsonenko DG, Mironov YV. Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers. Russian Chemical Bulletin. 2020 Jul 1;69(7):1264-1271. doi: 10.1007/s11172-020-2896-2

Author

Litvinova, Y. M. ; Gayfulin, Y. M. ; Samsonenko, D. G. et al. / Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers. In: Russian Chemical Bulletin. 2020 ; Vol. 69, No. 7. pp. 1264-1271.

BibTeX

@article{dde2fcd5655f41feb5934f2a070680be,
title = "Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers",
abstract = "The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.",
keywords = "cluster complex, crystal structure, lanthanides, metal-organic frameworks, rhenium, CONVERSION, COMPLEXES, CRYSTAL-STRUCTURES, NANOPARTICLES, LUMINESCENT, LANTHANIDE, COORDINATION POLYMERS, CLUSTER",
author = "Litvinova, {Y. M.} and Gayfulin, {Y. M.} and Samsonenko, {D. G.} and Mironov, {Y. V.}",
year = "2020",
month = jul,
day = "1",
doi = "10.1007/s11172-020-2896-2",
language = "English",
volume = "69",
pages = "1264--1271",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "7",

}

RIS

TY - JOUR

T1 - Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers

AU - Litvinova, Y. M.

AU - Gayfulin, Y. M.

AU - Samsonenko, D. G.

AU - Mironov, Y. V.

PY - 2020/7/1

Y1 - 2020/7/1

N2 - The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.

AB - The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.

KW - cluster complex

KW - crystal structure

KW - lanthanides

KW - metal-organic frameworks

KW - rhenium

KW - CONVERSION

KW - COMPLEXES

KW - CRYSTAL-STRUCTURES

KW - NANOPARTICLES

KW - LUMINESCENT

KW - LANTHANIDE

KW - COORDINATION POLYMERS

KW - CLUSTER

UR - http://www.scopus.com/inward/record.url?scp=85090147801&partnerID=8YFLogxK

U2 - 10.1007/s11172-020-2896-2

DO - 10.1007/s11172-020-2896-2

M3 - Article

AN - SCOPUS:85090147801

VL - 69

SP - 1264

EP - 1271

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 7

ER -

ID: 25285502