Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers. / Litvinova, Y. M.; Gayfulin, Y. M.; Samsonenko, D. G. и др.
в: Russian Chemical Bulletin, Том 69, № 7, 01.07.2020, стр. 1264-1271.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers
AU - Litvinova, Y. M.
AU - Gayfulin, Y. M.
AU - Samsonenko, D. G.
AU - Mironov, Y. V.
PY - 2020/7/1
Y1 - 2020/7/1
N2 - The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.
AB - The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.
KW - cluster complex
KW - crystal structure
KW - lanthanides
KW - metal-organic frameworks
KW - rhenium
KW - CONVERSION
KW - COMPLEXES
KW - CRYSTAL-STRUCTURES
KW - NANOPARTICLES
KW - LUMINESCENT
KW - LANTHANIDE
KW - COORDINATION POLYMERS
KW - CLUSTER
UR - http://www.scopus.com/inward/record.url?scp=85090147801&partnerID=8YFLogxK
U2 - 10.1007/s11172-020-2896-2
DO - 10.1007/s11172-020-2896-2
M3 - Article
AN - SCOPUS:85090147801
VL - 69
SP - 1264
EP - 1271
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 7
ER -
ID: 25285502