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Luminescent twelve-nuclear rhenium clusters. / Gayfulin, Yakov M.; Brylev, Konstantin A.; Ryzhikov, Maxim R. et al.

In: Dalton Transactions, Vol. 48, No. 33, 07.09.2019, p. 12522-12530.

Research output: Contribution to journal › Article › peer-review

Harvard

Gayfulin, YM, Brylev, KA, Ryzhikov, MR, Samsonenko, DG, Kitamura, N & Mironov, YV 2019, 'Luminescent twelve-nuclear rhenium clusters', Dalton Transactions, vol. 48, no. 33, pp. 12522-12530. https://doi.org/10.1039/c9dt02352f

APA

Gayfulin, Y. M., Brylev, K. A., Ryzhikov, M. R., Samsonenko, D. G., Kitamura, N., & Mironov, Y. V. (2019). Luminescent twelve-nuclear rhenium clusters. Dalton Transactions, 48(33), 12522-12530. https://doi.org/10.1039/c9dt02352f

Vancouver

Gayfulin YM, Brylev KA, Ryzhikov MR, Samsonenko DG, Kitamura N, Mironov YV. Luminescent twelve-nuclear rhenium clusters. Dalton Transactions. 2019 Sept 7;48(33):12522-12530. doi: 10.1039/c9dt02352f

Author

Gayfulin, Yakov M. ; Brylev, Konstantin A. ; Ryzhikov, Maxim R. et al. / Luminescent twelve-nuclear rhenium clusters. In: Dalton Transactions. 2019 ; Vol. 48, No. 33. pp. 12522-12530.

BibTeX

@article{18b821759e06477a9984c6af6d0632e9,
title = "Luminescent twelve-nuclear rhenium clusters",
abstract = "The first luminescent twelve-nuclear rhenium cluster complexes were obtained. Three new clusters, namely, [Re12CS14(μ-Cl)3Cl6]5-, [Re12CS14(μ-Br)3Cl6]5- and [Re12CS14(μ-Br)3Br6]5-, were synthesized using the non-isovalent substitution of μ-O ligands within the {Re12CS14(μ-O)3}0 cluster core by halide anions. The geometry of the new clusters was investigated by X-ray structural analysis, and the electronic structures were evaluated by the use of DFT calculations. It was found that compounds based on these anions showed red luminescence in both the solid state and solution that was never observed before for previously studied twelve-nuclear rhenium clusters.",
keywords = "HEXARHENIUM(III) CLUSTERS, COMPLEXES, REDOX, LIGANDS, FAMILY, SE, BR, CL, CHEMISTRY, EMISSION",
author = "Gayfulin, {Yakov M.} and Brylev, {Konstantin A.} and Ryzhikov, {Maxim R.} and Samsonenko, {Denis G.} and Noboru Kitamura and Mironov, {Yuri V.}",
year = "2019",
month = sep,
day = "7",
doi = "10.1039/c9dt02352f",
language = "English",
volume = "48",
pages = "12522--12530",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "33",

}

RIS

TY - JOUR

T1 - Luminescent twelve-nuclear rhenium clusters

AU - Gayfulin, Yakov M.

AU - Brylev, Konstantin A.

AU - Ryzhikov, Maxim R.

AU - Samsonenko, Denis G.

AU - Kitamura, Noboru

AU - Mironov, Yuri V.

PY - 2019/9/7

Y1 - 2019/9/7

N2 - The first luminescent twelve-nuclear rhenium cluster complexes were obtained. Three new clusters, namely, [Re12CS14(μ-Cl)3Cl6]5-, [Re12CS14(μ-Br)3Cl6]5- and [Re12CS14(μ-Br)3Br6]5-, were synthesized using the non-isovalent substitution of μ-O ligands within the {Re12CS14(μ-O)3}0 cluster core by halide anions. The geometry of the new clusters was investigated by X-ray structural analysis, and the electronic structures were evaluated by the use of DFT calculations. It was found that compounds based on these anions showed red luminescence in both the solid state and solution that was never observed before for previously studied twelve-nuclear rhenium clusters.

AB - The first luminescent twelve-nuclear rhenium cluster complexes were obtained. Three new clusters, namely, [Re12CS14(μ-Cl)3Cl6]5-, [Re12CS14(μ-Br)3Cl6]5- and [Re12CS14(μ-Br)3Br6]5-, were synthesized using the non-isovalent substitution of μ-O ligands within the {Re12CS14(μ-O)3}0 cluster core by halide anions. The geometry of the new clusters was investigated by X-ray structural analysis, and the electronic structures were evaluated by the use of DFT calculations. It was found that compounds based on these anions showed red luminescence in both the solid state and solution that was never observed before for previously studied twelve-nuclear rhenium clusters.

KW - HEXARHENIUM(III) CLUSTERS

KW - COMPLEXES

KW - REDOX

KW - LIGANDS

KW - FAMILY

KW - SE

KW - BR

KW - CL

KW - CHEMISTRY

KW - EMISSION

UR - http://www.scopus.com/inward/record.url?scp=85071002534&partnerID=8YFLogxK

U2 - 10.1039/c9dt02352f

DO - 10.1039/c9dt02352f

M3 - Article

C2 - 31364655

AN - SCOPUS:85071002534

VL - 48

SP - 12522

EP - 12530

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 33

ER -

ID: 21343817