Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Luminescent twelve-nuclear rhenium clusters. / Gayfulin, Yakov M.; Brylev, Konstantin A.; Ryzhikov, Maxim R. и др.
в: Dalton Transactions, Том 48, № 33, 07.09.2019, стр. 12522-12530.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Luminescent twelve-nuclear rhenium clusters
AU - Gayfulin, Yakov M.
AU - Brylev, Konstantin A.
AU - Ryzhikov, Maxim R.
AU - Samsonenko, Denis G.
AU - Kitamura, Noboru
AU - Mironov, Yuri V.
PY - 2019/9/7
Y1 - 2019/9/7
N2 - The first luminescent twelve-nuclear rhenium cluster complexes were obtained. Three new clusters, namely, [Re12CS14(μ-Cl)3Cl6]5-, [Re12CS14(μ-Br)3Cl6]5- and [Re12CS14(μ-Br)3Br6]5-, were synthesized using the non-isovalent substitution of μ-O ligands within the {Re12CS14(μ-O)3}0 cluster core by halide anions. The geometry of the new clusters was investigated by X-ray structural analysis, and the electronic structures were evaluated by the use of DFT calculations. It was found that compounds based on these anions showed red luminescence in both the solid state and solution that was never observed before for previously studied twelve-nuclear rhenium clusters.
AB - The first luminescent twelve-nuclear rhenium cluster complexes were obtained. Three new clusters, namely, [Re12CS14(μ-Cl)3Cl6]5-, [Re12CS14(μ-Br)3Cl6]5- and [Re12CS14(μ-Br)3Br6]5-, were synthesized using the non-isovalent substitution of μ-O ligands within the {Re12CS14(μ-O)3}0 cluster core by halide anions. The geometry of the new clusters was investigated by X-ray structural analysis, and the electronic structures were evaluated by the use of DFT calculations. It was found that compounds based on these anions showed red luminescence in both the solid state and solution that was never observed before for previously studied twelve-nuclear rhenium clusters.
KW - HEXARHENIUM(III) CLUSTERS
KW - COMPLEXES
KW - REDOX
KW - LIGANDS
KW - FAMILY
KW - SE
KW - BR
KW - CL
KW - CHEMISTRY
KW - EMISSION
UR - http://www.scopus.com/inward/record.url?scp=85071002534&partnerID=8YFLogxK
U2 - 10.1039/c9dt02352f
DO - 10.1039/c9dt02352f
M3 - Article
C2 - 31364655
AN - SCOPUS:85071002534
VL - 48
SP - 12522
EP - 12530
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 33
ER -
ID: 21343817