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Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition. / Podyacheva, Olga Y.; Bulushev, Dmitri A.; Suboch, Arina N. et al.

In: ChemSusChem, Vol. 11, No. 21, 09.11.2018, p. 3724-3727.

Research output: Contribution to journal › Article › peer-review

Harvard

Podyacheva, OY, Bulushev, DA, Suboch, AN, Svintsitskiy, DA, Lisitsyn, AS, Modin, E, Chuvilin, A, Gerasimov, EY, Sobolev, VI & Parmon, VN 2018, 'Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition', ChemSusChem, vol. 11, no. 21, pp. 3724-3727. https://doi.org/10.1002/cssc.201801679

APA

Podyacheva, O. Y., Bulushev, D. A., Suboch, A. N., Svintsitskiy, D. A., Lisitsyn, A. S., Modin, E., Chuvilin, A., Gerasimov, E. Y., Sobolev, V. I., & Parmon, V. N. (2018). Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition. ChemSusChem, 11(21), 3724-3727. https://doi.org/10.1002/cssc.201801679

Vancouver

Podyacheva OY, Bulushev DA, Suboch AN, Svintsitskiy DA, Lisitsyn AS, Modin E et al. Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition. ChemSusChem. 2018 Nov 9;11(21):3724-3727. doi: 10.1002/cssc.201801679

Author

Podyacheva, Olga Y. ; Bulushev, Dmitri A. ; Suboch, Arina N. et al. / Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition. In: ChemSusChem. 2018 ; Vol. 11, No. 21. pp. 3724-3727.

BibTeX

@article{08d0b4e87cbf4b989a41e7c1474ac56f,
title = "Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition",
abstract = "Single-atom catalysts with ionic Pd active sites supported on nitrogen-doped carbon nanotubes have been synthesized with a palladium content of 0.2–0.5 wt %. The Pd sites exhibited unexpectedly high stability up to 500 °C in a hydrogen atmosphere which was explained by coordination of the Pd ions by nitrogen-containing fragments of graphene layers. The active sites showed a high rate of gas-phase formic acid decomposition yielding hydrogen. An increase in Pd content was accompanied by the formation of metallic nanoparticles with a size of 1.2–1.4 nm and by a decrease in the catalytic activity. The high stability of the single-atom Pd sites opens possibilities for using such catalysts in high-temperature reactions.",
keywords = "carbon nanotubes, doping, formic acid, palladium, single-atom catalyst, CAPACITY PROPERTIES, NANOFIBERS, ELECTRICAL-CONDUCTIVITY, HETEROGENEOUS CATALYSIS, NANOPARTICLES, DEHYDROGENATION, NITROGEN, CONSEQUENCES, HYDROGEN-PRODUCTION, METAL",
author = "Podyacheva, {Olga Y.} and Bulushev, {Dmitri A.} and Suboch, {Arina N.} and Svintsitskiy, {Dmitry A.} and Lisitsyn, {Alexander S.} and Evgeny Modin and Andrey Chuvilin and Gerasimov, {Evgeny Y.} and Sobolev, {Vladimir I.} and Parmon, {Valentin N.}",
note = "{\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2018",
month = nov,
day = "9",
doi = "10.1002/cssc.201801679",
language = "English",
volume = "11",
pages = "3724--3727",
journal = "ChemSusChem",
issn = "1864-5631",
publisher = "Wiley-VCH Verlag",
number = "21",

}

RIS

TY - JOUR

T1 - Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition

AU - Podyacheva, Olga Y.

AU - Bulushev, Dmitri A.

AU - Suboch, Arina N.

AU - Svintsitskiy, Dmitry A.

AU - Lisitsyn, Alexander S.

AU - Modin, Evgeny

AU - Chuvilin, Andrey

AU - Gerasimov, Evgeny Y.

AU - Sobolev, Vladimir I.

AU - Parmon, Valentin N.

N1 - © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2018/11/9

Y1 - 2018/11/9

N2 - Single-atom catalysts with ionic Pd active sites supported on nitrogen-doped carbon nanotubes have been synthesized with a palladium content of 0.2–0.5 wt %. The Pd sites exhibited unexpectedly high stability up to 500 °C in a hydrogen atmosphere which was explained by coordination of the Pd ions by nitrogen-containing fragments of graphene layers. The active sites showed a high rate of gas-phase formic acid decomposition yielding hydrogen. An increase in Pd content was accompanied by the formation of metallic nanoparticles with a size of 1.2–1.4 nm and by a decrease in the catalytic activity. The high stability of the single-atom Pd sites opens possibilities for using such catalysts in high-temperature reactions.

AB - Single-atom catalysts with ionic Pd active sites supported on nitrogen-doped carbon nanotubes have been synthesized with a palladium content of 0.2–0.5 wt %. The Pd sites exhibited unexpectedly high stability up to 500 °C in a hydrogen atmosphere which was explained by coordination of the Pd ions by nitrogen-containing fragments of graphene layers. The active sites showed a high rate of gas-phase formic acid decomposition yielding hydrogen. An increase in Pd content was accompanied by the formation of metallic nanoparticles with a size of 1.2–1.4 nm and by a decrease in the catalytic activity. The high stability of the single-atom Pd sites opens possibilities for using such catalysts in high-temperature reactions.

KW - carbon nanotubes

KW - doping

KW - formic acid

KW - palladium

KW - single-atom catalyst

KW - CAPACITY PROPERTIES

KW - NANOFIBERS

KW - ELECTRICAL-CONDUCTIVITY

KW - HETEROGENEOUS CATALYSIS

KW - NANOPARTICLES

KW - DEHYDROGENATION

KW - NITROGEN

KW - CONSEQUENCES

KW - HYDROGEN-PRODUCTION

KW - METAL

UR - http://www.scopus.com/inward/record.url?scp=85053425956&partnerID=8YFLogxK

U2 - 10.1002/cssc.201801679

DO - 10.1002/cssc.201801679

M3 - Article

C2 - 30175551

AN - SCOPUS:85053425956

VL - 11

SP - 3724

EP - 3727

JO - ChemSusChem

JF - ChemSusChem

SN - 1864-5631

IS - 21

ER -

ID: 16599420