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Emission tuning in Re(I) complexes : Expanding heterocyclic ligands and/or introduction of perfluorinated ligands. / Abramov, Pavel A.; Brylev, Konstantin A.; Vorob'ev, Aleksei Yu et al.

In: Polyhedron, Vol. 137, 24.11.2017, p. 231-237.

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Abramov PA, Brylev KA, Vorob'ev AY, Gatilov YV, Borodkin GI, Kitamura N et al. Emission tuning in Re(I) complexes: Expanding heterocyclic ligands and/or introduction of perfluorinated ligands. Polyhedron. 2017 Nov 24;137:231-237. doi: 10.1016/j.poly.2017.08.046

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@article{ad6ef3e52e1c49d2a72992d1960af2d3,
title = "Emission tuning in Re(I) complexes: Expanding heterocyclic ligands and/or introduction of perfluorinated ligands",
abstract = "Reactions of new heterocyclic ligands 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a]quinolin-9-ol (L-OH), 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Py) and 2-methyl-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Me) with [Re(CO)5Br] in toluene afforded the complexes of the general formula [(L)Re(CO)3Br]. Substitution of the Br− ligand in [(L)Re(CO)3Br] by C3F7COO− leads to [(L)Re(CO)3(OOCC3F7)] and results in increased emission lifetime.",
keywords = "Diimine, Luminescence, Perfluorinated ligands, Rhenium",
author = "Abramov, {Pavel A.} and Brylev, {Konstantin A.} and Vorob'ev, {Aleksei Yu} and Gatilov, {Yuriy V.} and Borodkin, {Gennadiy I.} and Noboru Kitamura and Sokolov, {Maxim N.}",
year = "2017",
month = nov,
day = "24",
doi = "10.1016/j.poly.2017.08.046",
language = "English",
volume = "137",
pages = "231--237",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Emission tuning in Re(I) complexes

T2 - Expanding heterocyclic ligands and/or introduction of perfluorinated ligands

AU - Abramov, Pavel A.

AU - Brylev, Konstantin A.

AU - Vorob'ev, Aleksei Yu

AU - Gatilov, Yuriy V.

AU - Borodkin, Gennadiy I.

AU - Kitamura, Noboru

AU - Sokolov, Maxim N.

PY - 2017/11/24

Y1 - 2017/11/24

N2 - Reactions of new heterocyclic ligands 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a]quinolin-9-ol (L-OH), 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Py) and 2-methyl-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Me) with [Re(CO)5Br] in toluene afforded the complexes of the general formula [(L)Re(CO)3Br]. Substitution of the Br− ligand in [(L)Re(CO)3Br] by C3F7COO− leads to [(L)Re(CO)3(OOCC3F7)] and results in increased emission lifetime.

AB - Reactions of new heterocyclic ligands 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a]quinolin-9-ol (L-OH), 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Py) and 2-methyl-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Me) with [Re(CO)5Br] in toluene afforded the complexes of the general formula [(L)Re(CO)3Br]. Substitution of the Br− ligand in [(L)Re(CO)3Br] by C3F7COO− leads to [(L)Re(CO)3(OOCC3F7)] and results in increased emission lifetime.

KW - Diimine

KW - Luminescence

KW - Perfluorinated ligands

KW - Rhenium

UR - http://www.scopus.com/inward/record.url?scp=85029307470&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2017.08.046

DO - 10.1016/j.poly.2017.08.046

M3 - Article

AN - SCOPUS:85029307470

VL - 137

SP - 231

EP - 237

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 9048081