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Complexes of {W6I8}4+ Clusters with Carboxylates : Preparation, Electrochemistry, and Luminescence. / Sokolov, Maxim N.; Brylev, Konstantin A.; Abramov, Pavel A. et al.

In: European Journal of Inorganic Chemistry, Vol. 2017, No. 35, 25.09.2017, p. 4131-4137.

Research output: Contribution to journal › Article › peer-review

Harvard

Sokolov, MN, Brylev, KA, Abramov, PA, Gallyamov, MR, Novozhilov, IN, Kitamura, N & Mikhaylov, MA 2017, 'Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence', European Journal of Inorganic Chemistry, vol. 2017, no. 35, pp. 4131-4137. https://doi.org/10.1002/ejic.201700618

APA

Sokolov, M. N., Brylev, K. A., Abramov, P. A., Gallyamov, M. R., Novozhilov, I. N., Kitamura, N., & Mikhaylov, M. A. (2017). Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence. European Journal of Inorganic Chemistry, 2017(35), 4131-4137. https://doi.org/10.1002/ejic.201700618

Vancouver

Sokolov MN, Brylev KA, Abramov PA, Gallyamov MR, Novozhilov IN, Kitamura N et al. Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence. European Journal of Inorganic Chemistry. 2017 Sept 25;2017(35):4131-4137. doi: 10.1002/ejic.201700618

Author

Sokolov, Maxim N. ; Brylev, Konstantin A. ; Abramov, Pavel A. et al. / Complexes of {W6I8}4+ Clusters with Carboxylates : Preparation, Electrochemistry, and Luminescence. In: European Journal of Inorganic Chemistry. 2017 ; Vol. 2017, No. 35. pp. 4131-4137.

BibTeX

@article{15d21bd3e4444e0d82dcc49085510251,
title = "Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence",
abstract = "The reactions between (Bu4N)2[{W6I8}I6] (1) and silver carboxylates RCOOAg in CH2Cl2 afforded new luminescent carboxylate complexes (Bu4N)2[{W6I8}(RCOO)6] [R = CH3 (2), C6H5 (3), C2F5 (4), C3F7 (5), C6F5 (6)]. The complexes were characterized by single-crystal X-ray diffraction, elemental analysis, cyclic voltammetry, and IR and NMR spectroscopy. Complexes 1–6 all exhibit intense and long-lived photoluminescence. The carboxylate complexes undergo reversible electrochemical oxidation in two consecutive one-electron steps.",
keywords = "Carboxylate ligands, Cluster compounds, Electrochemistry, Luminescence, Tungsten",
author = "Sokolov, {Maxim N.} and Brylev, {Konstantin A.} and Abramov, {Pavel A.} and Gallyamov, {Marsel R.} and Novozhilov, {Igor N.} and N. Kitamura and Mikhaylov, {Maxim A.}",
note = "Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2017",
month = sep,
day = "25",
doi = "10.1002/ejic.201700618",
language = "English",
volume = "2017",
pages = "4131--4137",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "35",

}

RIS

TY - JOUR

T1 - Complexes of {W6I8}4+ Clusters with Carboxylates

T2 - Preparation, Electrochemistry, and Luminescence

AU - Sokolov, Maxim N.

AU - Brylev, Konstantin A.

AU - Abramov, Pavel A.

AU - Gallyamov, Marsel R.

AU - Novozhilov, Igor N.

AU - Kitamura, N.

AU - Mikhaylov, Maxim A.

N1 - Publisher Copyright: © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2017/9/25

Y1 - 2017/9/25

N2 - The reactions between (Bu4N)2[{W6I8}I6] (1) and silver carboxylates RCOOAg in CH2Cl2 afforded new luminescent carboxylate complexes (Bu4N)2[{W6I8}(RCOO)6] [R = CH3 (2), C6H5 (3), C2F5 (4), C3F7 (5), C6F5 (6)]. The complexes were characterized by single-crystal X-ray diffraction, elemental analysis, cyclic voltammetry, and IR and NMR spectroscopy. Complexes 1–6 all exhibit intense and long-lived photoluminescence. The carboxylate complexes undergo reversible electrochemical oxidation in two consecutive one-electron steps.

AB - The reactions between (Bu4N)2[{W6I8}I6] (1) and silver carboxylates RCOOAg in CH2Cl2 afforded new luminescent carboxylate complexes (Bu4N)2[{W6I8}(RCOO)6] [R = CH3 (2), C6H5 (3), C2F5 (4), C3F7 (5), C6F5 (6)]. The complexes were characterized by single-crystal X-ray diffraction, elemental analysis, cyclic voltammetry, and IR and NMR spectroscopy. Complexes 1–6 all exhibit intense and long-lived photoluminescence. The carboxylate complexes undergo reversible electrochemical oxidation in two consecutive one-electron steps.

KW - Carboxylate ligands

KW - Cluster compounds

KW - Electrochemistry

KW - Luminescence

KW - Tungsten

UR - http://www.scopus.com/inward/record.url?scp=85029799099&partnerID=8YFLogxK

U2 - 10.1002/ejic.201700618

DO - 10.1002/ejic.201700618

M3 - Article

AN - SCOPUS:85029799099

VL - 2017

SP - 4131

EP - 4137

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 35

ER -

ID: 9906785