Complexes of {W6I8}4+ Clusters with Carboxylates › Обзор исследований

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Complexes of {W₆I₈}⁴⁺ Clusters with Carboxylates : Preparation, Electrochemistry, and Luminescence. / Sokolov, Maxim N.; Brylev, Konstantin A.; Abramov, Pavel A. и др.

в: European Journal of Inorganic Chemistry, Том 2017, № 35, 25.09.2017, стр. 4131-4137.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Sokolov, MN , Brylev, KA, Abramov, PA, Gallyamov, MR, Novozhilov, IN, Kitamura, N & Mikhaylov, MA 2017, 'Complexes of {W₆I₈}⁴⁺ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence', European Journal of Inorganic Chemistry, Том. 2017, № 35, стр. 4131-4137. https://doi.org/10.1002/ejic.201700618

APA

Sokolov, M. N., Brylev, K. A., Abramov, P. A., Gallyamov, M. R., Novozhilov, I. N., Kitamura, N., & Mikhaylov, M. A. (2017). Complexes of {W₆I₈}⁴⁺ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence. European Journal of Inorganic Chemistry, 2017(35), 4131-4137. https://doi.org/10.1002/ejic.201700618

Vancouver

Sokolov MN , Brylev KA, Abramov PA, Gallyamov MR, Novozhilov IN, Kitamura N и др. Complexes of {W₆I₈}⁴⁺ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence. European Journal of Inorganic Chemistry. 2017 сент. 25;2017(35):4131-4137. doi: 10.1002/ejic.201700618

Author

Sokolov, Maxim N. ; Brylev, Konstantin A. ; Abramov, Pavel A. и др. / Complexes of {W₆I₈}⁴⁺ Clusters with Carboxylates : Preparation, Electrochemistry, and Luminescence. в: European Journal of Inorganic Chemistry. 2017 ; Том 2017, № 35. стр. 4131-4137.

BibTeX

@article{15d21bd3e4444e0d82dcc49085510251,

title = "Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence",

abstract = "The reactions between (Bu4N)2[{W6I8}I6] (1) and silver carboxylates RCOOAg in CH2Cl2 afforded new luminescent carboxylate complexes (Bu4N)2[{W6I8}(RCOO)6] [R = CH3 (2), C6H5 (3), C2F5 (4), C3F7 (5), C6F5 (6)]. The complexes were characterized by single-crystal X-ray diffraction, elemental analysis, cyclic voltammetry, and IR and NMR spectroscopy. Complexes 1–6 all exhibit intense and long-lived photoluminescence. The carboxylate complexes undergo reversible electrochemical oxidation in two consecutive one-electron steps.",

keywords = "Carboxylate ligands, Cluster compounds, Electrochemistry, Luminescence, Tungsten",

author = "Sokolov, {Maxim N.} and Brylev, {Konstantin A.} and Abramov, {Pavel A.} and Gallyamov, {Marsel R.} and Novozhilov, {Igor N.} and N. Kitamura and Mikhaylov, {Maxim A.}",

note = "Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2017",

month = sep,

day = "25",

doi = "10.1002/ejic.201700618",

language = "English",

volume = "2017",

pages = "4131--4137",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "35",

}

RIS

TY - JOUR

T1 - Complexes of {W6I8}4+ Clusters with Carboxylates

T2 - Preparation, Electrochemistry, and Luminescence

AU - Sokolov, Maxim N.

AU - Brylev, Konstantin A.

AU - Abramov, Pavel A.

AU - Gallyamov, Marsel R.

AU - Novozhilov, Igor N.

AU - Kitamura, N.

AU - Mikhaylov, Maxim A.

PY - 2017/9/25

Y1 - 2017/9/25

N2 - The reactions between (Bu4N)2[{W6I8}I6] (1) and silver carboxylates RCOOAg in CH2Cl2 afforded new luminescent carboxylate complexes (Bu4N)2[{W6I8}(RCOO)6] [R = CH3 (2), C6H5 (3), C2F5 (4), C3F7 (5), C6F5 (6)]. The complexes were characterized by single-crystal X-ray diffraction, elemental analysis, cyclic voltammetry, and IR and NMR spectroscopy. Complexes 1–6 all exhibit intense and long-lived photoluminescence. The carboxylate complexes undergo reversible electrochemical oxidation in two consecutive one-electron steps.

AB - The reactions between (Bu4N)2[{W6I8}I6] (1) and silver carboxylates RCOOAg in CH2Cl2 afforded new luminescent carboxylate complexes (Bu4N)2[{W6I8}(RCOO)6] [R = CH3 (2), C6H5 (3), C2F5 (4), C3F7 (5), C6F5 (6)]. The complexes were characterized by single-crystal X-ray diffraction, elemental analysis, cyclic voltammetry, and IR and NMR spectroscopy. Complexes 1–6 all exhibit intense and long-lived photoluminescence. The carboxylate complexes undergo reversible electrochemical oxidation in two consecutive one-electron steps.

KW - Carboxylate ligands

KW - Cluster compounds

KW - Electrochemistry

KW - Luminescence

KW - Tungsten

UR - http://www.scopus.com/inward/record.url?scp=85029799099&partnerID=8YFLogxK

U2 - 10.1002/ejic.201700618

DO - 10.1002/ejic.201700618

M3 - Article

AN - SCOPUS:85029799099

VL - 2017

SP - 4131

EP - 4137

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 35

ER -

ID: 9906785