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Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+. / Petrov, P. A.; Ryzhikov, M. R.; Kuratieva, N. V. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 42, No. 3, 01.03.2016, p. 196-200.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Ryzhikov, MR, Kuratieva, NV & Konchenko, SN 2016, 'Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 42, no. 3, pp. 196-200. https://doi.org/10.1134/S1070328416020056

APA

Petrov, P. A., Ryzhikov, M. R., Kuratieva, N. V., & Konchenko, S. N. (2016). Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 42(3), 196-200. https://doi.org/10.1134/S1070328416020056

Vancouver

Petrov PA, Ryzhikov MR, Kuratieva NV, Konchenko SN. Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2016 Mar 1;42(3):196-200. doi: 10.1134/S1070328416020056

Author

Petrov, P. A. ; Ryzhikov, M. R. ; Kuratieva, N. V. et al. / Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2016 ; Vol. 42, No. 3. pp. 196-200.

BibTeX

@article{1d607829ef224ee285c9d294c1424982,
title = "Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+",
abstract = "The reaction of cluster [Re3S4(Dppe)3Br3]Br with sodium tert-butyl thiolate affords trinuclear cationic cluster [Re3S5(Dppe)3]Br (I). The oxidation of cluster I with air gives [Re3S4(SO2)(Dppe)3]Cl (II), which is characterized by X-ray diffraction analysis in the form of solvate II · 3.5CH2Cl2 (CIF file CCDC 1401732). The DFT calculations indicate the triplet ground state of the [Re3S5(Dppe)3]+ cation and a significant spin density on the equatorial sulfide ligands, favoring the oxidation of the cluster.",
author = "Petrov, {P. A.} and Ryzhikov, {M. R.} and Kuratieva, {N. V.} and Konchenko, {S. N.}",
year = "2016",
month = mar,
day = "1",
doi = "10.1134/S1070328416020056",
language = "English",
volume = "42",
pages = "196--200",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "3",

}

RIS

TY - JOUR

T1 - Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+

AU - Petrov, P. A.

AU - Ryzhikov, M. R.

AU - Kuratieva, N. V.

AU - Konchenko, S. N.

PY - 2016/3/1

Y1 - 2016/3/1

N2 - The reaction of cluster [Re3S4(Dppe)3Br3]Br with sodium tert-butyl thiolate affords trinuclear cationic cluster [Re3S5(Dppe)3]Br (I). The oxidation of cluster I with air gives [Re3S4(SO2)(Dppe)3]Cl (II), which is characterized by X-ray diffraction analysis in the form of solvate II · 3.5CH2Cl2 (CIF file CCDC 1401732). The DFT calculations indicate the triplet ground state of the [Re3S5(Dppe)3]+ cation and a significant spin density on the equatorial sulfide ligands, favoring the oxidation of the cluster.

AB - The reaction of cluster [Re3S4(Dppe)3Br3]Br with sodium tert-butyl thiolate affords trinuclear cationic cluster [Re3S5(Dppe)3]Br (I). The oxidation of cluster I with air gives [Re3S4(SO2)(Dppe)3]Cl (II), which is characterized by X-ray diffraction analysis in the form of solvate II · 3.5CH2Cl2 (CIF file CCDC 1401732). The DFT calculations indicate the triplet ground state of the [Re3S5(Dppe)3]+ cation and a significant spin density on the equatorial sulfide ligands, favoring the oxidation of the cluster.

UR - http://www.scopus.com/inward/record.url?scp=84962110815&partnerID=8YFLogxK

U2 - 10.1134/S1070328416020056

DO - 10.1134/S1070328416020056

M3 - Article

AN - SCOPUS:84962110815

VL - 42

SP - 196

EP - 200

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 3

ER -

ID: 25414304