Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+. / Petrov, P. A.; Ryzhikov, M. R.; Kuratieva, N. V. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 42, № 3, 01.03.2016, стр. 196-200.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+
AU - Petrov, P. A.
AU - Ryzhikov, M. R.
AU - Kuratieva, N. V.
AU - Konchenko, S. N.
PY - 2016/3/1
Y1 - 2016/3/1
N2 - The reaction of cluster [Re3S4(Dppe)3Br3]Br with sodium tert-butyl thiolate affords trinuclear cationic cluster [Re3S5(Dppe)3]Br (I). The oxidation of cluster I with air gives [Re3S4(SO2)(Dppe)3]Cl (II), which is characterized by X-ray diffraction analysis in the form of solvate II · 3.5CH2Cl2 (CIF file CCDC 1401732). The DFT calculations indicate the triplet ground state of the [Re3S5(Dppe)3]+ cation and a significant spin density on the equatorial sulfide ligands, favoring the oxidation of the cluster.
AB - The reaction of cluster [Re3S4(Dppe)3Br3]Br with sodium tert-butyl thiolate affords trinuclear cationic cluster [Re3S5(Dppe)3]Br (I). The oxidation of cluster I with air gives [Re3S4(SO2)(Dppe)3]Cl (II), which is characterized by X-ray diffraction analysis in the form of solvate II · 3.5CH2Cl2 (CIF file CCDC 1401732). The DFT calculations indicate the triplet ground state of the [Re3S5(Dppe)3]+ cation and a significant spin density on the equatorial sulfide ligands, favoring the oxidation of the cluster.
UR - http://www.scopus.com/inward/record.url?scp=84962110815&partnerID=8YFLogxK
U2 - 10.1134/S1070328416020056
DO - 10.1134/S1070328416020056
M3 - Article
AN - SCOPUS:84962110815
VL - 42
SP - 196
EP - 200
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 3
ER -
ID: 25414304