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Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+ [Hg2I6]2− and {[2,6−(OMe)2C6H3]3SbME}2+ [Hg2I4]2− · : Synthesis and Structure. / Egorova, I. V.; Zhidkov, V. V.; Grinishak, I. P. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 64, No. 1, 01.01.2019, p. 28-35.

Research output: Contribution to journal › Article › peer-review

Harvard

Egorova, IV, Zhidkov, VV, Grinishak, IP, Bagryanskaya, IY, Pervukhina, NV, El’tsov, IV & Kurat’eva, NV 2019, 'Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+ [Hg2I6]2− and {[2,6−(OMe)2C6H3]3SbME}2+ [Hg2I4]2− ·: Synthesis and Structure', Russian Journal of Inorganic Chemistry, vol. 64, no. 1, pp. 28-35. https://doi.org/10.1134/S0036023619010078

APA

Egorova, I. V., Zhidkov, V. V., Grinishak, I. P., Bagryanskaya, I. Y., Pervukhina, N. V., El’tsov, I. V., & Kurat’eva, N. V. (2019). Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+ [Hg2I6]2− and {[2,6−(OMe)2C6H3]3SbME}2+ [Hg2I4]2− ·: Synthesis and Structure. Russian Journal of Inorganic Chemistry, 64(1), 28-35. https://doi.org/10.1134/S0036023619010078

Vancouver

Egorova IV, Zhidkov VV, Grinishak IP, Bagryanskaya IY, Pervukhina NV, El’tsov IV et al. Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+ [Hg2I6]2− and {[2,6−(OMe)2C6H3]3SbME}2+ [Hg2I4]2− ·: Synthesis and Structure. Russian Journal of Inorganic Chemistry. 2019 Jan 1;64(1):28-35. doi: 10.1134/S0036023619010078

Author

Egorova, I. V. ; Zhidkov, V. V. ; Grinishak, I. P. et al. / Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+ [Hg2I6]2− and {[2,6−(OMe)2C6H3]3SbME}2+ [Hg2I4]2− · : Synthesis and Structure. In: Russian Journal of Inorganic Chemistry. 2019 ; Vol. 64, No. 1. pp. 28-35.

BibTeX

@article{f143791953d14b1db4d12264d792ba7b,
title = "Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+ [Hg2I6]2− and {[2,6−(OMe)2C6H3]3SbME}2+ [Hg2I4]2− ·: Synthesis and Structure",
abstract = " It has been established that ethyl iodoacelate and 1,4-diiodobutane alkylate triarylantimony Ar 3 Sb with the formation of [Ar 3 SbCH 2 C(O)OEt] + I − and [Ar 3 Sb(CH 2 ) 4 I] + I − , [Ar3Sb(CH2)4I]+I−,[Ar3Sb(CH2)4SbAr3]+I2−, where Ar = 2,6-(OMe) 2 C 6 H 3 . The complexes [Ar3SbCH2C(O)OEt]2+[Hg2I6]2− and [Ar3SbMe]2+[HgI4]2− · DMSO have been synthesized by the reaction of [Ar 3 SbCH 2 C(O)OEt]+I − and [Ar 3 SbMe]+I − with mercury diiodide and studied by X-ray diffraction. The antimony and iodine atoms have a distorted tetrahedral coordination. The CSbC and IHgI angles are ranged within 103.28(14)°–116.68(14)°, 103.7(4)°–115.5(4)° and 98.122(9)°–125.590(12)°, 102.66(2)°–115.64(2)°, respectively. ",
keywords = "1,4-diiodobutane, ethyl iodoacetate, mercury diiodide, nuclear magnetic resonance, tris(2,6-dimethoxyphenyl) (ethoxycarbonylmethyl) antimony iodide, tris(2,6-dimethoxyphenyl) antimony, tris(2,6-dimethoxyphenyl)methyl antimony iodide, X-ray diffraction analysis, ANTIMONY DERIVATIVES, DONOR-ACCEPTOR COMPLEXES, tris(2,6-dimethoxyphenyl) methyl antimony iodide, DERIVATIVES",
author = "Egorova, {I. V.} and Zhidkov, {V. V.} and Grinishak, {I. P.} and Bagryanskaya, {I. Yu} and Pervukhina, {N. V.} and El{\textquoteright}tsov, {I. V.} and Kurat{\textquoteright}eva, {N. V.}",
year = "2019",
month = jan,
day = "1",
doi = "10.1134/S0036023619010078",
language = "English",
volume = "64",
pages = "28--35",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

RIS

TY - JOUR

T1 - Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+ [Hg2I6]2− and {[2,6−(OMe)2C6H3]3SbME}2+ [Hg2I4]2− ·

T2 - Synthesis and Structure

AU - Egorova, I. V.

AU - Zhidkov, V. V.

AU - Grinishak, I. P.

AU - Bagryanskaya, I. Yu

AU - Pervukhina, N. V.

AU - El’tsov, I. V.

AU - Kurat’eva, N. V.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - It has been established that ethyl iodoacelate and 1,4-diiodobutane alkylate triarylantimony Ar 3 Sb with the formation of [Ar 3 SbCH 2 C(O)OEt] + I − and [Ar 3 Sb(CH 2 ) 4 I] + I − , [Ar3Sb(CH2)4I]+I−,[Ar3Sb(CH2)4SbAr3]+I2−, where Ar = 2,6-(OMe) 2 C 6 H 3 . The complexes [Ar3SbCH2C(O)OEt]2+[Hg2I6]2− and [Ar3SbMe]2+[HgI4]2− · DMSO have been synthesized by the reaction of [Ar 3 SbCH 2 C(O)OEt]+I − and [Ar 3 SbMe]+I − with mercury diiodide and studied by X-ray diffraction. The antimony and iodine atoms have a distorted tetrahedral coordination. The CSbC and IHgI angles are ranged within 103.28(14)°–116.68(14)°, 103.7(4)°–115.5(4)° and 98.122(9)°–125.590(12)°, 102.66(2)°–115.64(2)°, respectively.

AB - It has been established that ethyl iodoacelate and 1,4-diiodobutane alkylate triarylantimony Ar 3 Sb with the formation of [Ar 3 SbCH 2 C(O)OEt] + I − and [Ar 3 Sb(CH 2 ) 4 I] + I − , [Ar3Sb(CH2)4I]+I−,[Ar3Sb(CH2)4SbAr3]+I2−, where Ar = 2,6-(OMe) 2 C 6 H 3 . The complexes [Ar3SbCH2C(O)OEt]2+[Hg2I6]2− and [Ar3SbMe]2+[HgI4]2− · DMSO have been synthesized by the reaction of [Ar 3 SbCH 2 C(O)OEt]+I − and [Ar 3 SbMe]+I − with mercury diiodide and studied by X-ray diffraction. The antimony and iodine atoms have a distorted tetrahedral coordination. The CSbC and IHgI angles are ranged within 103.28(14)°–116.68(14)°, 103.7(4)°–115.5(4)° and 98.122(9)°–125.590(12)°, 102.66(2)°–115.64(2)°, respectively.

KW - 1,4-diiodobutane

KW - ethyl iodoacetate

KW - mercury diiodide

KW - nuclear magnetic resonance

KW - tris(2,6-dimethoxyphenyl) (ethoxycarbonylmethyl) antimony iodide

KW - tris(2,6-dimethoxyphenyl) antimony

KW - tris(2,6-dimethoxyphenyl)methyl antimony iodide

KW - X-ray diffraction analysis

KW - ANTIMONY DERIVATIVES

KW - DONOR-ACCEPTOR COMPLEXES

KW - tris(2,6-dimethoxyphenyl) methyl antimony iodide

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85065406243&partnerID=8YFLogxK

U2 - 10.1134/S0036023619010078

DO - 10.1134/S0036023619010078

M3 - Article

AN - SCOPUS:85065406243

VL - 64

SP - 28

EP - 35

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 1

ER -

ID: 20161615