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XPS experimental and DFT investigations on solid solutions of Mo1-: XRexS2 (0 < x < 0.20). / Dalmatova, Svetlana A.; Fedorenko, Anastasiya D.; Mazalov, Lev N. et al.

In: Nanoscale, Vol. 10, No. 21, 31.05.2018, p. 10232-10240.

Research output: Contribution to journal › Article › peer-review

Harvard

Dalmatova, SA, Fedorenko, AD, Mazalov, LN, Asanov, IP, Ledneva, AY, Tarasenko, MS, Enyashin, AN, Zaikovskii, VI & Fedorov, VE 2018, 'XPS experimental and DFT investigations on solid solutions of Mo1-: XRexS2 (0 < x < 0.20)', Nanoscale, vol. 10, no. 21, pp. 10232-10240. https://doi.org/10.1039/c8nr01661e

APA

Dalmatova, S. A., Fedorenko, A. D., Mazalov, L. N., Asanov, I. P., Ledneva, A. Y., Tarasenko, M. S., Enyashin, A. N., Zaikovskii, V. I., & Fedorov, V. E. (2018). XPS experimental and DFT investigations on solid solutions of Mo1-: XRexS2 (0 < x < 0.20). Nanoscale, 10(21), 10232-10240. https://doi.org/10.1039/c8nr01661e

Vancouver

Dalmatova SA, Fedorenko AD, Mazalov LN, Asanov IP, Ledneva AY, Tarasenko MS et al. XPS experimental and DFT investigations on solid solutions of Mo1-: XRexS2 (0 < x < 0.20). Nanoscale. 2018 May 31;10(21):10232-10240. doi: 10.1039/c8nr01661e

Author

Dalmatova, Svetlana A. ; Fedorenko, Anastasiya D. ; Mazalov, Lev N. et al. / XPS experimental and DFT investigations on solid solutions of Mo1-: XRexS2 (0 < x < 0.20). In: Nanoscale. 2018 ; Vol. 10, No. 21. pp. 10232-10240.

BibTeX

@article{ed357561d6e04210bf4b2389150711c3,
title = "XPS experimental and DFT investigations on solid solutions of Mo1-: XRexS2 (0 < x < 0.20)",
abstract = "The synthesis, characterization, experimental X-ray photoelectron spectra (XPS) and density-functional theory (DFT) investigations on solid solutions of Mo1-xRexS2 (x = 0.05, 0.10, 0.15 and 0.20) are reported herein. It is shown that even at a low concentration of dopant Re atoms, clustering occurs. At an Re concentration of 5% the formation of dimer-like impregnations is observed. An increase in the dopant concentration leads to an increase in the amount of clustered rhenium atoms and to the formation of rhombic clusters. The absence of magnetism within the studied Mo1-xRexS2 solid solutions allowed us to suggest a mechanism for the distribution of rhenium inside molybdenum disulphide through the initial formation of rhenium disulphide and its subsequent spreading.",
keywords = "TRANSITION-METAL DICHALCOGENIDES, DENSITY-FUNCTIONAL THEORY, ELECTRONIC-PROPERTIES, MOLYBDENUM-DISULFIDE, TUNGSTEN DISELENIDE, SINGLE-CRYSTALS, PARTICLE-SIZE, MOS2, STABILITY, ADSORPTION",
author = "Dalmatova, {Svetlana A.} and Fedorenko, {Anastasiya D.} and Mazalov, {Lev N.} and Asanov, {Igor P.} and Ledneva, {Alexandra Yu} and Tarasenko, {Mariya S.} and Enyashin, {Andrey N.} and Zaikovskii, {Vladimir I.} and Fedorov, {Vladimir E.}",
year = "2018",
month = may,
day = "31",
doi = "10.1039/c8nr01661e",
language = "English",
volume = "10",
pages = "10232--10240",
journal = "Nanoscale",
issn = "2040-3364",
publisher = "Royal Society of Chemistry",
number = "21",

}

RIS

TY - JOUR

T1 - XPS experimental and DFT investigations on solid solutions of Mo1-: XRexS2 (0 < x < 0.20)

AU - Dalmatova, Svetlana A.

AU - Fedorenko, Anastasiya D.

AU - Mazalov, Lev N.

AU - Asanov, Igor P.

AU - Ledneva, Alexandra Yu

AU - Tarasenko, Mariya S.

AU - Enyashin, Andrey N.

AU - Zaikovskii, Vladimir I.

AU - Fedorov, Vladimir E.

PY - 2018/5/31

Y1 - 2018/5/31

N2 - The synthesis, characterization, experimental X-ray photoelectron spectra (XPS) and density-functional theory (DFT) investigations on solid solutions of Mo1-xRexS2 (x = 0.05, 0.10, 0.15 and 0.20) are reported herein. It is shown that even at a low concentration of dopant Re atoms, clustering occurs. At an Re concentration of 5% the formation of dimer-like impregnations is observed. An increase in the dopant concentration leads to an increase in the amount of clustered rhenium atoms and to the formation of rhombic clusters. The absence of magnetism within the studied Mo1-xRexS2 solid solutions allowed us to suggest a mechanism for the distribution of rhenium inside molybdenum disulphide through the initial formation of rhenium disulphide and its subsequent spreading.

AB - The synthesis, characterization, experimental X-ray photoelectron spectra (XPS) and density-functional theory (DFT) investigations on solid solutions of Mo1-xRexS2 (x = 0.05, 0.10, 0.15 and 0.20) are reported herein. It is shown that even at a low concentration of dopant Re atoms, clustering occurs. At an Re concentration of 5% the formation of dimer-like impregnations is observed. An increase in the dopant concentration leads to an increase in the amount of clustered rhenium atoms and to the formation of rhombic clusters. The absence of magnetism within the studied Mo1-xRexS2 solid solutions allowed us to suggest a mechanism for the distribution of rhenium inside molybdenum disulphide through the initial formation of rhenium disulphide and its subsequent spreading.

KW - TRANSITION-METAL DICHALCOGENIDES

KW - DENSITY-FUNCTIONAL THEORY

KW - ELECTRONIC-PROPERTIES

KW - MOLYBDENUM-DISULFIDE

KW - TUNGSTEN DISELENIDE

KW - SINGLE-CRYSTALS

KW - PARTICLE-SIZE

KW - MOS2

KW - STABILITY

KW - ADSORPTION

UR - http://www.scopus.com/inward/record.url?scp=85047931026&partnerID=8YFLogxK

U2 - 10.1039/c8nr01661e

DO - 10.1039/c8nr01661e

M3 - Article

C2 - 29790553

AN - SCOPUS:85047931026

VL - 10

SP - 10232

EP - 10240

JO - Nanoscale

JF - Nanoscale

SN - 2040-3364

IS - 21

ER -

ID: 13754761