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Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications. / Ivanov, Anton A.; Konovalov, Dmitry I.; Pozmogova, Tatiana N. et al.

In: Inorganic Chemistry Frontiers, Vol. 6, No. 4, 01.04.2019, p. 882-892.

Research output: Contribution to journal › Article › peer-review

Harvard

Ivanov, AA, Konovalov, DI, Pozmogova, TN, Solovieva, AO, Melnikov, AR, Brylev, KA, Kuratieva, NV, Yanshole, VV, Kirakci, K, Lang, K, Cheltygmasheva, SN, Kitamura, N, Shestopalova, LV, Mironov, YV & Shestopalov, MA 2019, 'Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications', Inorganic Chemistry Frontiers, vol. 6, no. 4, pp. 882-892. https://doi.org/10.1039/c8qi01216d

APA

Ivanov, A. A., Konovalov, D. I., Pozmogova, T. N., Solovieva, A. O., Melnikov, A. R., Brylev, K. A., Kuratieva, N. V., Yanshole, V. V., Kirakci, K., Lang, K., Cheltygmasheva, S. N., Kitamura, N., Shestopalova, L. V., Mironov, Y. V., & Shestopalov, M. A. (2019). Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications. Inorganic Chemistry Frontiers, 6(4), 882-892. https://doi.org/10.1039/c8qi01216d

Vancouver

Ivanov AA, Konovalov DI, Pozmogova TN, Solovieva AO, Melnikov AR, Brylev KA et al. Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications. Inorganic Chemistry Frontiers. 2019 Apr 1;6(4):882-892. doi: 10.1039/c8qi01216d

Author

Ivanov, Anton A. ; Konovalov, Dmitry I. ; Pozmogova, Tatiana N. et al. / Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications. In: Inorganic Chemistry Frontiers. 2019 ; Vol. 6, No. 4. pp. 882-892.

BibTeX

@article{f1eec265920542d9aee410414539dd18,
title = "Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications",
abstract = " The development of water-soluble hexanuclear cluster complexes of low toxicity is a promising task due to their potential biomedical applications such as bioimaging and photodynamic therapy. Herein, we present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties. These cluster complexes, namely [{Re 6 Q 8 }(PPh 2 CH 2 CH 2 COO) 6 ] 4- (Q = S (1); Se, (2)), have the least cytotoxicity among all the tested hexanuclear metal-clusters, are capable of penetrating into cells and exhibit moderate photodynamic toxicity toward Hep-2 cells. ",
author = "Ivanov, {Anton A.} and Konovalov, {Dmitry I.} and Pozmogova, {Tatiana N.} and Solovieva, {Anastasiya O.} and Melnikov, {Anatoly R.} and Brylev, {Konstantin A.} and Kuratieva, {Natalia V.} and Yanshole, {Vadim V.} and Kaplan Kirakci and Kamil Lang and Cheltygmasheva, {Svetlana N.} and Noboru Kitamura and Shestopalova, {Lidiya V.} and Mironov, {Yuri V.} and Shestopalov, {Michael A.}",
note = "Publisher Copyright: {\textcopyright} 2019 the Partner Organisations.",
year = "2019",
month = apr,
day = "1",
doi = "10.1039/c8qi01216d",
language = "English",
volume = "6",
pages = "882--892",
journal = "Inorganic Chemistry Frontiers",
issn = "2052-1545",
publisher = "Royal Society of Chemistry",
number = "4",

}

RIS

TY - JOUR

T1 - Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications

AU - Ivanov, Anton A.

AU - Konovalov, Dmitry I.

AU - Pozmogova, Tatiana N.

AU - Solovieva, Anastasiya O.

AU - Melnikov, Anatoly R.

AU - Brylev, Konstantin A.

AU - Kuratieva, Natalia V.

AU - Yanshole, Vadim V.

AU - Kirakci, Kaplan

AU - Lang, Kamil

AU - Cheltygmasheva, Svetlana N.

AU - Kitamura, Noboru

AU - Shestopalova, Lidiya V.

AU - Mironov, Yuri V.

AU - Shestopalov, Michael A.

N1 - Publisher Copyright: © 2019 the Partner Organisations.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - The development of water-soluble hexanuclear cluster complexes of low toxicity is a promising task due to their potential biomedical applications such as bioimaging and photodynamic therapy. Herein, we present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties. These cluster complexes, namely [{Re 6 Q 8 }(PPh 2 CH 2 CH 2 COO) 6 ] 4- (Q = S (1); Se, (2)), have the least cytotoxicity among all the tested hexanuclear metal-clusters, are capable of penetrating into cells and exhibit moderate photodynamic toxicity toward Hep-2 cells.

AB - The development of water-soluble hexanuclear cluster complexes of low toxicity is a promising task due to their potential biomedical applications such as bioimaging and photodynamic therapy. Herein, we present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties. These cluster complexes, namely [{Re 6 Q 8 }(PPh 2 CH 2 CH 2 COO) 6 ] 4- (Q = S (1); Se, (2)), have the least cytotoxicity among all the tested hexanuclear metal-clusters, are capable of penetrating into cells and exhibit moderate photodynamic toxicity toward Hep-2 cells.

UR - http://www.scopus.com/inward/record.url?scp=85063429787&partnerID=8YFLogxK

U2 - 10.1039/c8qi01216d

DO - 10.1039/c8qi01216d

M3 - Article

AN - SCOPUS:85063429787

VL - 6

SP - 882

EP - 892

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

SN - 2052-1545

IS - 4

ER -

ID: 19341614