Standard

Volatile asymmetric fluorinated (O^N)-chelated palladium complexes : From ligand sources to MOCVD application. / Nikolaeva, N. S.; Kuratieva, N. V.; Vikulova, E. S. et al.

In: Polyhedron, Vol. 171, 01.10.2019, p. 455-463.

Research output: Contribution to journal › Article › peer-review

Harvard

Nikolaeva, NS, Kuratieva, NV, Vikulova, ES, Stabnikov, PA & Morozova, NB 2019, 'Volatile asymmetric fluorinated (O^N)-chelated palladium complexes: From ligand sources to MOCVD application', Polyhedron, vol. 171, pp. 455-463. https://doi.org/10.1016/j.poly.2019.07.039

APA

Nikolaeva, N. S., Kuratieva, N. V., Vikulova, E. S., Stabnikov, P. A., & Morozova, N. B. (2019). Volatile asymmetric fluorinated (O^N)-chelated palladium complexes: From ligand sources to MOCVD application. Polyhedron, 171, 455-463. https://doi.org/10.1016/j.poly.2019.07.039

Vancouver

Nikolaeva NS, Kuratieva NV, Vikulova ES, Stabnikov PA, Morozova NB. Volatile asymmetric fluorinated (O^N)-chelated palladium complexes: From ligand sources to MOCVD application. Polyhedron. 2019 Oct 1;171:455-463. doi: 10.1016/j.poly.2019.07.039

Author

Nikolaeva, N. S. ; Kuratieva, N. V. ; Vikulova, E. S. et al. / Volatile asymmetric fluorinated (O^N)-chelated palladium complexes : From ligand sources to MOCVD application. In: Polyhedron. 2019 ; Vol. 171. pp. 455-463.

BibTeX

@article{2a8be963cf3e421da41c95bddc5e58e1,
title = "Volatile asymmetric fluorinated (O^N)-chelated palladium complexes: From ligand sources to MOCVD application",
abstract = "The work deals with the volatile asymmetric palladium complexes of β-ketoiminate-type as a new direction to design the effective partially fluorinated (O^N)-chelated precursors for metal–organic chemical vapor deposition (MOCVD). To determine the effect of the substituent on the donor nitrogen atom, [Pd(CF3COCHCN(R)CH3)2]2 complexes with R = CH3 (Mei-tfac) and N(CH3)2 (dmht) were synthesized and characterized by elemental analysis, IR and NMR spectroscopy. The molecular and crystal structures of the complexes as well as the initial ligand sources HMei-tfac and Hdmht were determined by single-crystal XRD. The obtained a new crystallographic and thermal (TG/DTA) information combined with the crystal lattice energy calculations allowed to reveal the features of the N-substituted fluorinated complexes in comparison with their non-fluorinated analogs. The possibility of using the proposed compounds as MOCVD precursors was experimentally confirmed.",
keywords = "Beta-ketoiminates, MOCVD, Palladium volatile precursors, Single crystal X-ray diffraction analysis, Thermal properties",
author = "Nikolaeva, {N. S.} and Kuratieva, {N. V.} and Vikulova, {E. S.} and Stabnikov, {P. A.} and Morozova, {N. B.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",
year = "2019",
month = oct,
day = "1",
doi = "10.1016/j.poly.2019.07.039",
language = "English",
volume = "171",
pages = "455--463",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Volatile asymmetric fluorinated (O^N)-chelated palladium complexes

T2 - From ligand sources to MOCVD application

AU - Nikolaeva, N. S.

AU - Kuratieva, N. V.

AU - Vikulova, E. S.

AU - Stabnikov, P. A.

AU - Morozova, N. B.

N1 - Publisher Copyright: © 2019 Elsevier Ltd

PY - 2019/10/1

Y1 - 2019/10/1

N2 - The work deals with the volatile asymmetric palladium complexes of β-ketoiminate-type as a new direction to design the effective partially fluorinated (O^N)-chelated precursors for metal–organic chemical vapor deposition (MOCVD). To determine the effect of the substituent on the donor nitrogen atom, [Pd(CF3COCHCN(R)CH3)2]2 complexes with R = CH3 (Mei-tfac) and N(CH3)2 (dmht) were synthesized and characterized by elemental analysis, IR and NMR spectroscopy. The molecular and crystal structures of the complexes as well as the initial ligand sources HMei-tfac and Hdmht were determined by single-crystal XRD. The obtained a new crystallographic and thermal (TG/DTA) information combined with the crystal lattice energy calculations allowed to reveal the features of the N-substituted fluorinated complexes in comparison with their non-fluorinated analogs. The possibility of using the proposed compounds as MOCVD precursors was experimentally confirmed.

AB - The work deals with the volatile asymmetric palladium complexes of β-ketoiminate-type as a new direction to design the effective partially fluorinated (O^N)-chelated precursors for metal–organic chemical vapor deposition (MOCVD). To determine the effect of the substituent on the donor nitrogen atom, [Pd(CF3COCHCN(R)CH3)2]2 complexes with R = CH3 (Mei-tfac) and N(CH3)2 (dmht) were synthesized and characterized by elemental analysis, IR and NMR spectroscopy. The molecular and crystal structures of the complexes as well as the initial ligand sources HMei-tfac and Hdmht were determined by single-crystal XRD. The obtained a new crystallographic and thermal (TG/DTA) information combined with the crystal lattice energy calculations allowed to reveal the features of the N-substituted fluorinated complexes in comparison with their non-fluorinated analogs. The possibility of using the proposed compounds as MOCVD precursors was experimentally confirmed.

KW - Beta-ketoiminates

KW - MOCVD

KW - Palladium volatile precursors

KW - Single crystal X-ray diffraction analysis

KW - Thermal properties

UR - http://www.scopus.com/inward/record.url?scp=85070887180&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2019.07.039

DO - 10.1016/j.poly.2019.07.039

M3 - Article

AN - SCOPUS:85070887180

VL - 171

SP - 455

EP - 463

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 21336649