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Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization. / Edeleva, Mariya; Morozov, Denis; Parkhomenko, Dmitriy et al.

In: Chemical Communications, Vol. 55, No. 2, 01.01.2019, p. 190-193.

Research output: Contribution to journal › Article › peer-review

Harvard

Edeleva, M, Morozov, D, Parkhomenko, D, Polienko, Y, Iurchenkova, A, Kirilyuk, I & Bagryanskaya, E 2019, 'Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization', Chemical Communications, vol. 55, no. 2, pp. 190-193. https://doi.org/10.1039/C8CC08541B

APA

Edeleva, M., Morozov, D., Parkhomenko, D., Polienko, Y., Iurchenkova, A., Kirilyuk, I., & Bagryanskaya, E. (2019). Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization. Chemical Communications, 55(2), 190-193. https://doi.org/10.1039/C8CC08541B

Vancouver

Edeleva M, Morozov D, Parkhomenko D, Polienko Y, Iurchenkova A, Kirilyuk I et al. Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization. Chemical Communications. 2019 Jan 1;55(2):190-193. doi: 10.1039/C8CC08541B

Author

Edeleva, Mariya ; Morozov, Denis ; Parkhomenko, Dmitriy et al. / Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization. In: Chemical Communications. 2019 ; Vol. 55, No. 2. pp. 190-193.

BibTeX

@article{aa6af417031b473692e044ca322ebbc7,
title = "Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization",
abstract = "An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator.",
keywords = "ON BOND HOMOLYSIS, RADICAL POLYMERIZATION, IMIDAZOLINE SERIES, POLAR",
author = "Mariya Edeleva and Denis Morozov and Dmitriy Parkhomenko and Yulia Polienko and Anna Iurchenkova and Igor Kirilyuk and Elena Bagryanskaya",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",
year = "2019",
month = jan,
day = "1",
doi = "10.1039/C8CC08541B",
language = "English",
volume = "55",
pages = "190--193",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "2",

}

RIS

TY - JOUR

T1 - Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization

AU - Edeleva, Mariya

AU - Morozov, Denis

AU - Parkhomenko, Dmitriy

AU - Polienko, Yulia

AU - Iurchenkova, Anna

AU - Kirilyuk, Igor

AU - Bagryanskaya, Elena

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator.

AB - An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator.

KW - ON BOND HOMOLYSIS

KW - RADICAL POLYMERIZATION

KW - IMIDAZOLINE SERIES

KW - POLAR

UR - http://www.scopus.com/inward/record.url?scp=85058902122&partnerID=8YFLogxK

U2 - 10.1039/C8CC08541B

DO - 10.1039/C8CC08541B

M3 - Article

C2 - 30519689

AN - SCOPUS:85058902122

VL - 55

SP - 190

EP - 193

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 2

ER -

ID: 18066257