Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization. / Edeleva, Mariya; Morozov, Denis; Parkhomenko, Dmitriy и др.
в: Chemical Communications, Том 55, № 2, 01.01.2019, стр. 190-193.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization
AU - Edeleva, Mariya
AU - Morozov, Denis
AU - Parkhomenko, Dmitriy
AU - Polienko, Yulia
AU - Iurchenkova, Anna
AU - Kirilyuk, Igor
AU - Bagryanskaya, Elena
N1 - Publisher Copyright: © The Royal Society of Chemistry.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator.
AB - An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator.
KW - ON BOND HOMOLYSIS
KW - RADICAL POLYMERIZATION
KW - IMIDAZOLINE SERIES
KW - POLAR
UR - http://www.scopus.com/inward/record.url?scp=85058902122&partnerID=8YFLogxK
U2 - 10.1039/C8CC08541B
DO - 10.1039/C8CC08541B
M3 - Article
C2 - 30519689
AN - SCOPUS:85058902122
VL - 55
SP - 190
EP - 193
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 2
ER -
ID: 18066257