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Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal-Organic Frameworks. / Sapchenko, Sergey A.; Barsukova, Marina O.; Belosludov, Rodion V. et al.

In: Inorganic Chemistry, Vol. 58, No. 10, 20.05.2019, p. 6811-6820.

Research output: Contribution to journal › Article › peer-review

Harvard

Sapchenko, SA, Barsukova, MO, Belosludov, RV, Kovalenko, KA, Samsonenko, DG, Poryvaev, AS, Sheveleva, AM, Fedin, MV, Bogomyakov, AS, Dybtsev, DN, Schröder, M & Fedin, VP 2019, 'Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal-Organic Frameworks', Inorganic Chemistry, vol. 58, no. 10, pp. 6811-6820. https://doi.org/10.1021/acs.inorgchem.9b00016

APA

Sapchenko, S. A., Barsukova, M. O., Belosludov, R. V., Kovalenko, K. A., Samsonenko, D. G., Poryvaev, A. S., Sheveleva, A. M., Fedin, M. V., Bogomyakov, A. S., Dybtsev, D. N., Schröder, M., & Fedin, V. P. (2019). Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal-Organic Frameworks. Inorganic Chemistry, 58(10), 6811-6820. https://doi.org/10.1021/acs.inorgchem.9b00016

Vancouver

Sapchenko SA, Barsukova MO, Belosludov RV, Kovalenko KA, Samsonenko DG, Poryvaev AS et al. Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal-Organic Frameworks. Inorganic Chemistry. 2019 May 20;58(10):6811-6820. doi: 10.1021/acs.inorgchem.9b00016

Author

Sapchenko, Sergey A. ; Barsukova, Marina O. ; Belosludov, Rodion V. et al. / Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal-Organic Frameworks. In: Inorganic Chemistry. 2019 ; Vol. 58, No. 10. pp. 6811-6820.

BibTeX

@article{dc15daf582f4481f99ba114f9749ee9b,
title = "Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal-Organic Frameworks",
abstract = "Two new isostructural microporous coordination frameworks [Mn3(Hpdc)2(pdc)2] (1) and [Mg3(Hpdc)2(pdc)2] (2) (pdc2- = pyridine-2,4-dicarboxylate) showing primitive cubic (pcu) topology have been prepared and characterized. The pore aperture of the channels is too narrow for the efficient adsorption of N2; however, both compounds demonstrate substantially higher uptake of CO2 (119.9 mL·g-1 for 1 and 102.5 mL·g-1 for 2 at 195 K, 1 bar). Despite of their structural similarities, 2 shows a typical reversible type I isotherm for adsorption/desorption of CO2, while 1 features a two-step adsorption process with a very broad hysteresis between the adsorption and desorption curves. This behavior can be explained by a combination of density functional theory calculations, sorption, and X-ray diffraction analysis and gives insights into the further development of new sorbents showing adsorption/desorption hysteresis.",
author = "Sapchenko, {Sergey A.} and Barsukova, {Marina O.} and Belosludov, {Rodion V.} and Kovalenko, {Konstantin A.} and Samsonenko, {Denis G.} and Poryvaev, {Artem S.} and Sheveleva, {Alena M.} and Fedin, {Matvey V.} and Bogomyakov, {Artem S.} and Dybtsev, {Danil N.} and Martin Schr{\"o}der and Fedin, {Vladimir P.}",
year = "2019",
month = may,
day = "20",
doi = "10.1021/acs.inorgchem.9b00016",
language = "English",
volume = "58",
pages = "6811--6820",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "10",

}

RIS

TY - JOUR

T1 - Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal-Organic Frameworks

AU - Sapchenko, Sergey A.

AU - Barsukova, Marina O.

AU - Belosludov, Rodion V.

AU - Kovalenko, Konstantin A.

AU - Samsonenko, Denis G.

AU - Poryvaev, Artem S.

AU - Sheveleva, Alena M.

AU - Fedin, Matvey V.

AU - Bogomyakov, Artem S.

AU - Dybtsev, Danil N.

AU - Schröder, Martin

AU - Fedin, Vladimir P.

PY - 2019/5/20

Y1 - 2019/5/20

N2 - Two new isostructural microporous coordination frameworks [Mn3(Hpdc)2(pdc)2] (1) and [Mg3(Hpdc)2(pdc)2] (2) (pdc2- = pyridine-2,4-dicarboxylate) showing primitive cubic (pcu) topology have been prepared and characterized. The pore aperture of the channels is too narrow for the efficient adsorption of N2; however, both compounds demonstrate substantially higher uptake of CO2 (119.9 mL·g-1 for 1 and 102.5 mL·g-1 for 2 at 195 K, 1 bar). Despite of their structural similarities, 2 shows a typical reversible type I isotherm for adsorption/desorption of CO2, while 1 features a two-step adsorption process with a very broad hysteresis between the adsorption and desorption curves. This behavior can be explained by a combination of density functional theory calculations, sorption, and X-ray diffraction analysis and gives insights into the further development of new sorbents showing adsorption/desorption hysteresis.

AB - Two new isostructural microporous coordination frameworks [Mn3(Hpdc)2(pdc)2] (1) and [Mg3(Hpdc)2(pdc)2] (2) (pdc2- = pyridine-2,4-dicarboxylate) showing primitive cubic (pcu) topology have been prepared and characterized. The pore aperture of the channels is too narrow for the efficient adsorption of N2; however, both compounds demonstrate substantially higher uptake of CO2 (119.9 mL·g-1 for 1 and 102.5 mL·g-1 for 2 at 195 K, 1 bar). Despite of their structural similarities, 2 shows a typical reversible type I isotherm for adsorption/desorption of CO2, while 1 features a two-step adsorption process with a very broad hysteresis between the adsorption and desorption curves. This behavior can be explained by a combination of density functional theory calculations, sorption, and X-ray diffraction analysis and gives insights into the further development of new sorbents showing adsorption/desorption hysteresis.

UR - http://www.scopus.com/inward/record.url?scp=85066120811&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.9b00016

DO - 10.1021/acs.inorgchem.9b00016

M3 - Article

C2 - 31067041

AN - SCOPUS:85066120811

VL - 58

SP - 6811

EP - 6820

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 10

ER -

ID: 20158220