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The study of structural and morphological changes during thermal decomposition of Y-2(C2O4)(3)center dot 10H(2)O. / Gribov, P. A.; Matvienko, A. A.; Zakharov, B. A. et al.

In: Materials Today: Proceedings, Vol. 4, No. 11, 2017, p. 11470-11475.

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@article{1cbb4c23de4441fcb18887dee4d7c9a1,
title = "The study of structural and morphological changes during thermal decomposition of Y-2(C2O4)(3)center dot 10H(2)O",
abstract = "The study of structure and morphology changes during thermal decomposition of yttrium oxalate decahydrate Y-2(C2O4)(3)center dot 10H(2)O was presented in this paper. Thermal decomposition was found to include two main stages: dehydration and oxalate thermolysis. The effect of different dehydration conditions at hexahydrate formation stage on its structure and morphology was studied. Two polymorphic hexahydrate phases are shown to form. Structural transformations during dehydration were assumed to proceed by martensitic mechanism in both cases. Structural transformation mechanisms were suggested. The stages of oxalate thermolysis were determined and products at each stage were identified. Yttrium oxide as final product of decomposition was obtained. (C) 2017 Elsevier Ltd. All rights reserved.",
keywords = "yttrium oxalate decahydrate, structure transformation, martensitic transformation, thermal decomposition, yttrium oxide, YTTRIUM, OXALATES, SOLIDS, TRANSFORMATION, REACTIVITY, SCANDIUM, ELECTRON, ELEMENTS",
author = "Gribov, {P. A.} and Matvienko, {A. A.} and Zakharov, {B. A.} and Chizhik, {S. A.} and Sidelnikov, {A. A.}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd. Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd.; Russia-Japan Conference on Advanced Materials - Synthesis, Processing and Properties of Nanostructures (RJCAM) ; Conference date: 31-10-2016 Through 03-11-2016",
year = "2017",
doi = "10.1016/j.matpr.2017.09.031",
language = "English",
volume = "4",
pages = "11470--11475",
journal = "Materials Today: Proceedings",
issn = "2214-7853",
publisher = "Elsevier Science B.V.",
number = "11",

}

RIS

TY - JOUR

T1 - The study of structural and morphological changes during thermal decomposition of Y-2(C2O4)(3)center dot 10H(2)O

AU - Gribov, P. A.

AU - Matvienko, A. A.

AU - Zakharov, B. A.

AU - Chizhik, S. A.

AU - Sidelnikov, A. A.

N1 - Publisher Copyright: © 2017 Elsevier Ltd. Publisher Copyright: © 2017 Elsevier Ltd.

PY - 2017

Y1 - 2017

N2 - The study of structure and morphology changes during thermal decomposition of yttrium oxalate decahydrate Y-2(C2O4)(3)center dot 10H(2)O was presented in this paper. Thermal decomposition was found to include two main stages: dehydration and oxalate thermolysis. The effect of different dehydration conditions at hexahydrate formation stage on its structure and morphology was studied. Two polymorphic hexahydrate phases are shown to form. Structural transformations during dehydration were assumed to proceed by martensitic mechanism in both cases. Structural transformation mechanisms were suggested. The stages of oxalate thermolysis were determined and products at each stage were identified. Yttrium oxide as final product of decomposition was obtained. (C) 2017 Elsevier Ltd. All rights reserved.

AB - The study of structure and morphology changes during thermal decomposition of yttrium oxalate decahydrate Y-2(C2O4)(3)center dot 10H(2)O was presented in this paper. Thermal decomposition was found to include two main stages: dehydration and oxalate thermolysis. The effect of different dehydration conditions at hexahydrate formation stage on its structure and morphology was studied. Two polymorphic hexahydrate phases are shown to form. Structural transformations during dehydration were assumed to proceed by martensitic mechanism in both cases. Structural transformation mechanisms were suggested. The stages of oxalate thermolysis were determined and products at each stage were identified. Yttrium oxide as final product of decomposition was obtained. (C) 2017 Elsevier Ltd. All rights reserved.

KW - yttrium oxalate decahydrate

KW - structure transformation

KW - martensitic transformation

KW - thermal decomposition

KW - yttrium oxide

KW - YTTRIUM

KW - OXALATES

KW - SOLIDS

KW - TRANSFORMATION

KW - REACTIVITY

KW - SCANDIUM

KW - ELECTRON

KW - ELEMENTS

UR - http://www.scopus.com/inward/record.url?scp=85032022906&partnerID=8YFLogxK

U2 - 10.1016/j.matpr.2017.09.031

DO - 10.1016/j.matpr.2017.09.031

M3 - Article

AN - SCOPUS:85032022906

VL - 4

SP - 11470

EP - 11475

JO - Materials Today: Proceedings

JF - Materials Today: Proceedings

SN - 2214-7853

IS - 11

T2 - Russia-Japan Conference on Advanced Materials - Synthesis, Processing and Properties of Nanostructures (RJCAM)

Y2 - 31 October 2016 through 3 November 2016

ER -

ID: 9875788