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The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene. / Stoyanov, Evgenii S.; Stoyanova, Irina V.

In: ChemistrySelect, Vol. 5, No. 29, 05.08.2020, p. 9277-9280.

Research output: Contribution to journal › Article › peer-review

Harvard

Stoyanov, ES & Stoyanova, IV 2020, 'The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene', ChemistrySelect, vol. 5, no. 29, pp. 9277-9280. https://doi.org/10.1002/slct.202001852

APA

Stoyanov, E. S., & Stoyanova, I. V. (2020). The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene. ChemistrySelect, 5(29), 9277-9280. https://doi.org/10.1002/slct.202001852

Vancouver

Stoyanov ES, Stoyanova IV. The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene. ChemistrySelect. 2020 Aug 5;5(29):9277-9280. doi: 10.1002/slct.202001852

Author

Stoyanov, Evgenii S. ; Stoyanova, Irina V. / The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene. In: ChemistrySelect. 2020 ; Vol. 5, No. 29. pp. 9277-9280.

BibTeX

@article{367436c1fd4d497ebd16b065ca1b6fa4,
title = "The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene",
abstract = "The first two stages of the chemical interaction of a benzyl cation with a weak base, benzene, have been established. A key point in the reactivity of this cation is its ability to act as a strong protonating agent, turning itself to highly reactive carbene molecule, which then interacts with the available initial carbocation. The second step is mostly responsible for the high reactivity of the unsaturated carbocation. Further studies will show whether this mechanism is typical for saturated alkane and allyl-type carbocations.",
keywords = "Carbocations reactivity, IR spectroscopy, superacids, SOLVOLYSIS, VINYL-CATIONS, STABILIZATION, GENERATION",
author = "Stoyanov, {Evgenii S.} and Stoyanova, {Irina V.}",
year = "2020",
month = aug,
day = "5",
doi = "10.1002/slct.202001852",
language = "English",
volume = "5",
pages = "9277--9280",
journal = "ChemistrySelect",
issn = "2365-6549",
publisher = "Wiley-Blackwell",
number = "29",

}

RIS

TY - JOUR

T1 - The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene

AU - Stoyanov, Evgenii S.

AU - Stoyanova, Irina V.

PY - 2020/8/5

Y1 - 2020/8/5

N2 - The first two stages of the chemical interaction of a benzyl cation with a weak base, benzene, have been established. A key point in the reactivity of this cation is its ability to act as a strong protonating agent, turning itself to highly reactive carbene molecule, which then interacts with the available initial carbocation. The second step is mostly responsible for the high reactivity of the unsaturated carbocation. Further studies will show whether this mechanism is typical for saturated alkane and allyl-type carbocations.

AB - The first two stages of the chemical interaction of a benzyl cation with a weak base, benzene, have been established. A key point in the reactivity of this cation is its ability to act as a strong protonating agent, turning itself to highly reactive carbene molecule, which then interacts with the available initial carbocation. The second step is mostly responsible for the high reactivity of the unsaturated carbocation. Further studies will show whether this mechanism is typical for saturated alkane and allyl-type carbocations.

KW - Carbocations reactivity

KW - IR spectroscopy

KW - superacids

KW - SOLVOLYSIS

KW - VINYL-CATIONS

KW - STABILIZATION

KW - GENERATION

UR - http://www.scopus.com/inward/record.url?scp=85089200903&partnerID=8YFLogxK

U2 - 10.1002/slct.202001852

DO - 10.1002/slct.202001852

M3 - Article

AN - SCOPUS:85089200903

VL - 5

SP - 9277

EP - 9280

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

IS - 29

ER -

ID: 24966904