Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene. / Stoyanov, Evgenii S.; Stoyanova, Irina V.
в: ChemistrySelect, Том 5, № 29, 05.08.2020, стр. 9277-9280.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene
AU - Stoyanov, Evgenii S.
AU - Stoyanova, Irina V.
PY - 2020/8/5
Y1 - 2020/8/5
N2 - The first two stages of the chemical interaction of a benzyl cation with a weak base, benzene, have been established. A key point in the reactivity of this cation is its ability to act as a strong protonating agent, turning itself to highly reactive carbene molecule, which then interacts with the available initial carbocation. The second step is mostly responsible for the high reactivity of the unsaturated carbocation. Further studies will show whether this mechanism is typical for saturated alkane and allyl-type carbocations.
AB - The first two stages of the chemical interaction of a benzyl cation with a weak base, benzene, have been established. A key point in the reactivity of this cation is its ability to act as a strong protonating agent, turning itself to highly reactive carbene molecule, which then interacts with the available initial carbocation. The second step is mostly responsible for the high reactivity of the unsaturated carbocation. Further studies will show whether this mechanism is typical for saturated alkane and allyl-type carbocations.
KW - Carbocations reactivity
KW - IR spectroscopy
KW - superacids
KW - SOLVOLYSIS
KW - VINYL-CATIONS
KW - STABILIZATION
KW - GENERATION
UR - http://www.scopus.com/inward/record.url?scp=85089200903&partnerID=8YFLogxK
U2 - 10.1002/slct.202001852
DO - 10.1002/slct.202001852
M3 - Article
AN - SCOPUS:85089200903
VL - 5
SP - 9277
EP - 9280
JO - ChemistrySelect
JF - ChemistrySelect
SN - 2365-6549
IS - 29
ER -
ID: 24966904