The first example of a dysprosium–zirconium chalcogenide complex

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The first example of a dysprosium–zirconium chalcogenide complex. / Konokhova, A. Yu; Afonin, M. Yu; Sukhikh, T. S. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 5, 05.2021, p. 704-710.

Research output: Contribution to journal › Article › peer-review

Harvard

Konokhova, AY, Afonin, MY, Sukhikh, TS & Konchenko, SN 2021, 'The first example of a dysprosium–zirconium chalcogenide complex', Journal of Structural Chemistry, vol. 62, no. 5, pp. 704-710. https://doi.org/10.1134/S0022476621050061

APA

Konokhova, A. Y., Afonin, M. Y., Sukhikh, T. S., & Konchenko, S. N. (2021). The first example of a dysprosium–zirconium chalcogenide complex. Journal of Structural Chemistry, 62(5), 704-710. https://doi.org/10.1134/S0022476621050061

Vancouver

Konokhova AY, Afonin MY, Sukhikh TS, Konchenko SN. The first example of a dysprosium–zirconium chalcogenide complex. Journal of Structural Chemistry. 2021 May;62(5):704-710. doi: 10.1134/S0022476621050061

Author

Konokhova, A. Yu ; Afonin, M. Yu ; Sukhikh, T. S. et al. / The first example of a dysprosium–zirconium chalcogenide complex. In: Journal of Structural Chemistry. 2021 ; Vol. 62, No. 5. pp. 704-710.

BibTeX

@article{38b6cbfd3cb84a14a725718a8cf4c782,

title = "The first example of a dysprosium–zirconium chalcogenide complex",

abstract = "The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium [Cp'2Zr(SH)2](Cp′ = η5-t-BuC5H4) with basic Cp*2Dy(allyl)] a heterometallic [Cp'2Zr(μ-S)(μ3-S)DyCp*2]2 complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium Cp'2Zr(μ-S)2, being the decomposition product of [Cp'2Zr(SH)2] in solution, are also structurally characterized.",

keywords = "crystal structure, dysprosium, heterometal complexes, sulfur, zirconium",

author = "Konokhova, {A. Yu} and Afonin, {M. Yu} and Sukhikh, {T. S.} and Konchenko, {S. N.}",

note = "Funding Information: The work was supported by the Russian Science Foundation (grant No. 16-13-10294). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = may,

doi = "10.1134/S0022476621050061",

language = "English",

volume = "62",

pages = "704--710",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "5",

}

RIS

TY - JOUR

T1 - The first example of a dysprosium–zirconium chalcogenide complex

AU - Konokhova, A. Yu

AU - Afonin, M. Yu

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

PY - 2021/5

Y1 - 2021/5

N2 - The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium [Cp'2Zr(SH)2](Cp′ = η5-t-BuC5H4) with basic Cp*2Dy(allyl)] a heterometallic [Cp'2Zr(μ-S)(μ3-S)DyCp*2]2 complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium Cp'2Zr(μ-S)2, being the decomposition product of [Cp'2Zr(SH)2] in solution, are also structurally characterized.

AB - The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium [Cp'2Zr(SH)2](Cp′ = η5-t-BuC5H4) with basic Cp*2Dy(allyl)] a heterometallic [Cp'2Zr(μ-S)(μ3-S)DyCp*2]2 complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium Cp'2Zr(μ-S)2, being the decomposition product of [Cp'2Zr(SH)2] in solution, are also structurally characterized.

KW - crystal structure

KW - dysprosium

KW - heterometal complexes

KW - sulfur

KW - zirconium

UR - http://www.scopus.com/inward/record.url?scp=85108082155&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/caa9f047-9f63-36bf-874a-3aed15d0621e/

U2 - 10.1134/S0022476621050061

DO - 10.1134/S0022476621050061

M3 - Article

AN - SCOPUS:85108082155

VL - 62

SP - 704

EP - 710

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 34055347