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Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+. / Pronin, Aleksei S.; Gayfulin, Yakov M.; Smolentsev, Anton I. et al.

In: Journal of Cluster Science, Vol. 30, No. 5, 01.09.2019, p. 1253-1257.

Research output: Contribution to journal › Article › peer-review

Harvard

Pronin, AS, Gayfulin, YM, Smolentsev, AI & Mironov, YV 2019, 'Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+', Journal of Cluster Science, vol. 30, no. 5, pp. 1253-1257. https://doi.org/10.1007/s10876-019-01566-z

APA

Pronin, A. S., Gayfulin, Y. M., Smolentsev, A. I., & Mironov, Y. V. (2019). Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+. Journal of Cluster Science, 30(5), 1253-1257. https://doi.org/10.1007/s10876-019-01566-z

Vancouver

Pronin AS, Gayfulin YM, Smolentsev AI, Mironov YV. Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+. Journal of Cluster Science. 2019 Sept 1;30(5):1253-1257. doi: 10.1007/s10876-019-01566-z

Author

Pronin, Aleksei S. ; Gayfulin, Yakov M. ; Smolentsev, Anton I. et al. / Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+. In: Journal of Cluster Science. 2019 ; Vol. 30, No. 5. pp. 1253-1257.

BibTeX

@article{b4fd2504669c400fbb3859273279fed1,
title = "Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+",
abstract = " A high-temperature reactions of equimolar amounts of ReI 3 , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 O (2), respectively. Involvement of As 2 S 3 instead of the mixture of As and S resulted in the formation of a cluster complex K 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ 3 -As and µ 3 -Q (Q = S, Se) ligands. ",
keywords = "Arsenic, Chalcogen, Crystal structure, Cyanometallate, Heteroligand cluster",
author = "Pronin, {Aleksei S.} and Gayfulin, {Yakov M.} and Smolentsev, {Anton I.} and Mironov, {Yuri V.}",
year = "2019",
month = sep,
day = "1",
doi = "10.1007/s10876-019-01566-z",
language = "English",
volume = "30",
pages = "1253--1257",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "5",

}

RIS

TY - JOUR

T1 - Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+

AU - Pronin, Aleksei S.

AU - Gayfulin, Yakov M.

AU - Smolentsev, Anton I.

AU - Mironov, Yuri V.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - A high-temperature reactions of equimolar amounts of ReI 3 , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 O (2), respectively. Involvement of As 2 S 3 instead of the mixture of As and S resulted in the formation of a cluster complex K 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ 3 -As and µ 3 -Q (Q = S, Se) ligands.

AB - A high-temperature reactions of equimolar amounts of ReI 3 , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 O (2), respectively. Involvement of As 2 S 3 instead of the mixture of As and S resulted in the formation of a cluster complex K 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ 3 -As and µ 3 -Q (Q = S, Se) ligands.

KW - Arsenic

KW - Chalcogen

KW - Crystal structure

KW - Cyanometallate

KW - Heteroligand cluster

UR - http://www.scopus.com/inward/record.url?scp=85064889082&partnerID=8YFLogxK

U2 - 10.1007/s10876-019-01566-z

DO - 10.1007/s10876-019-01566-z

M3 - Article

AN - SCOPUS:85064889082

VL - 30

SP - 1253

EP - 1257

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 5

ER -

ID: 20049041