Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+. / Pronin, Aleksei S.; Gayfulin, Yakov M.; Smolentsev, Anton I. и др.
в: Journal of Cluster Science, Том 30, № 5, 01.09.2019, стр. 1253-1257.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+
AU - Pronin, Aleksei S.
AU - Gayfulin, Yakov M.
AU - Smolentsev, Anton I.
AU - Mironov, Yuri V.
PY - 2019/9/1
Y1 - 2019/9/1
N2 - A high-temperature reactions of equimolar amounts of ReI 3 , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 O (2), respectively. Involvement of As 2 S 3 instead of the mixture of As and S resulted in the formation of a cluster complex K 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ 3 -As and µ 3 -Q (Q = S, Se) ligands.
AB - A high-temperature reactions of equimolar amounts of ReI 3 , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 O (2), respectively. Involvement of As 2 S 3 instead of the mixture of As and S resulted in the formation of a cluster complex K 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ 3 -As and µ 3 -Q (Q = S, Se) ligands.
KW - Arsenic
KW - Chalcogen
KW - Crystal structure
KW - Cyanometallate
KW - Heteroligand cluster
UR - http://www.scopus.com/inward/record.url?scp=85064889082&partnerID=8YFLogxK
U2 - 10.1007/s10876-019-01566-z
DO - 10.1007/s10876-019-01566-z
M3 - Article
AN - SCOPUS:85064889082
VL - 30
SP - 1253
EP - 1257
JO - Journal of Cluster Science
JF - Journal of Cluster Science
SN - 1040-7278
IS - 5
ER -
ID: 20049041