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Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4⋅H2O. / Makhinya, Alexander N.; Korolkov, Ilya V.; Il’In, Maxim A. et al.

In: Journal of Chemical Sciences, Vol. 129, No. 4, 01.04.2017, p. 441-448.

Research output: Contribution to journal › Article › peer-review

Harvard

Makhinya, AN, Korolkov, IV, Il’In, MA, Baidina, IA, Plusnin, PE, Maximovski, EA, Beletskaya, EA & Alferova, NI 2017, 'Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4⋅H2O', Journal of Chemical Sciences, vol. 129, no. 4, pp. 441-448. https://doi.org/10.1007/s12039-017-1261-y

APA

Makhinya, A. N., Korolkov, I. V., Il’In, M. A., Baidina, I. A., Plusnin, P. E., Maximovski, E. A., Beletskaya, E. A., & Alferova, N. I. (2017). Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4⋅H2O. Journal of Chemical Sciences, 129(4), 441-448. https://doi.org/10.1007/s12039-017-1261-y

Vancouver

Makhinya AN, Korolkov IV, Il’In MA, Baidina IA, Plusnin PE, Maximovski EA et al. Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4⋅H2O. Journal of Chemical Sciences. 2017 Apr 1;129(4):441-448. doi: 10.1007/s12039-017-1261-y

Author

Makhinya, Alexander N. ; Korolkov, Ilya V. ; Il’In, Maxim A. et al. / Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4⋅H2O. In: Journal of Chemical Sciences. 2017 ; Vol. 129, No. 4. pp. 441-448.

BibTeX

@article{332432159727488894500e400e1507b3,
title = "Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4⋅H2O",
abstract = "The reaction of trans-[Ru(NO)Py 2Cl 2(OH)] with concentrated o-phosphoric acid, after washing the mixture with diethyl ether, gave trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅2H 3PO4 ⋅H2O (I) in nearly quantitative yield. The structure of this compound was determined by X-ray diffraction analysis: space group P-1. Washing of I with ethanol afforded the dihydrophosphate salt trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O (II) (yield 97%). The thermal decomposition of I and II in a helium atmosphere resulted in the formation of ruthenium phosphide RuP as a predominant component along with Ru 2P or RuP 2. Preliminary photoisomerization experiments for trans-[Ru(NO)Py 2Cl 2(OH)] and trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O suggested the presence of metastable states. DSC experiments have been carried out for both compounds. The measured kinetic parameters for the metastable decay for trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O were E a = 90.7 ± 2.4 kJ/mol, log 10(k0/sec −1) = 18.9 ±0.6, and T d = 217 K.",
keywords = "DSC, photoinduced linkage isomer, pyridine, Ruthenium nitrosyl complexes, ruthenium phosphide, X-ray crystallography-thermal analysis, SERIES, REDUCTION, CRYSTAL-STRUCTURE, COMPLEXES, LIGHT, INDUCED METASTABLE STATES",
author = "Makhinya, {Alexander N.} and Korolkov, {Ilya V.} and Il{\textquoteright}In, {Maxim A.} and Baidina, {Iraida A.} and Plusnin, {Pavel E.} and Maximovski, {Eugeni A.} and Beletskaya, {Elizaveta A.} and Alferova, {Nina I.}",
year = "2017",
month = apr,
day = "1",
doi = "10.1007/s12039-017-1261-y",
language = "English",
volume = "129",
pages = "441--448",
journal = "Journal of Chemical Sciences",
issn = "0974-3626",
publisher = "Indian Academy of Sciences",
number = "4",

}

RIS

TY - JOUR

T1 - Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4⋅H2O

AU - Makhinya, Alexander N.

AU - Korolkov, Ilya V.

AU - Il’In, Maxim A.

AU - Baidina, Iraida A.

AU - Plusnin, Pavel E.

AU - Maximovski, Eugeni A.

AU - Beletskaya, Elizaveta A.

AU - Alferova, Nina I.

PY - 2017/4/1

Y1 - 2017/4/1

N2 - The reaction of trans-[Ru(NO)Py 2Cl 2(OH)] with concentrated o-phosphoric acid, after washing the mixture with diethyl ether, gave trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅2H 3PO4 ⋅H2O (I) in nearly quantitative yield. The structure of this compound was determined by X-ray diffraction analysis: space group P-1. Washing of I with ethanol afforded the dihydrophosphate salt trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O (II) (yield 97%). The thermal decomposition of I and II in a helium atmosphere resulted in the formation of ruthenium phosphide RuP as a predominant component along with Ru 2P or RuP 2. Preliminary photoisomerization experiments for trans-[Ru(NO)Py 2Cl 2(OH)] and trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O suggested the presence of metastable states. DSC experiments have been carried out for both compounds. The measured kinetic parameters for the metastable decay for trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O were E a = 90.7 ± 2.4 kJ/mol, log 10(k0/sec −1) = 18.9 ±0.6, and T d = 217 K.

AB - The reaction of trans-[Ru(NO)Py 2Cl 2(OH)] with concentrated o-phosphoric acid, after washing the mixture with diethyl ether, gave trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅2H 3PO4 ⋅H2O (I) in nearly quantitative yield. The structure of this compound was determined by X-ray diffraction analysis: space group P-1. Washing of I with ethanol afforded the dihydrophosphate salt trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O (II) (yield 97%). The thermal decomposition of I and II in a helium atmosphere resulted in the formation of ruthenium phosphide RuP as a predominant component along with Ru 2P or RuP 2. Preliminary photoisomerization experiments for trans-[Ru(NO)Py 2Cl 2(OH)] and trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O suggested the presence of metastable states. DSC experiments have been carried out for both compounds. The measured kinetic parameters for the metastable decay for trans-[Ru(NO)Py 2Cl 2(H 2O)]H 2PO4 ⋅H2O were E a = 90.7 ± 2.4 kJ/mol, log 10(k0/sec −1) = 18.9 ±0.6, and T d = 217 K.

KW - DSC

KW - photoinduced linkage isomer

KW - pyridine

KW - Ruthenium nitrosyl complexes

KW - ruthenium phosphide

KW - X-ray crystallography-thermal analysis

KW - SERIES

KW - REDUCTION

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - LIGHT

KW - INDUCED METASTABLE STATES

UR - http://www.scopus.com/inward/record.url?scp=85018465164&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/1ae23326-b0b5-38a7-a67c-b1a493776bfe/

U2 - 10.1007/s12039-017-1261-y

DO - 10.1007/s12039-017-1261-y

M3 - Article

AN - SCOPUS:85018465164

VL - 129

SP - 441

EP - 448

JO - Journal of Chemical Sciences

JF - Journal of Chemical Sciences

SN - 0974-3626

IS - 4

ER -

ID: 10040232