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Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments. / Litvinova, Yulia M.; Gayfulin, Yakov M.; Bogomyakov, Artem S. et al.

In: Journal of Cluster Science, Vol. 28, No. 6, 01.11.2017, p. 3103-3114.

Research output: Contribution to journal › Article › peer-review

Harvard

Litvinova, YM, Gayfulin, YM, Bogomyakov, AS, Samsonenko, DG & Mironov, YV 2017, 'Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments', Journal of Cluster Science, vol. 28, no. 6, pp. 3103-3114. https://doi.org/10.1007/s10876-017-1276-z

APA

Litvinova, Y. M., Gayfulin, Y. M., Bogomyakov, A. S., Samsonenko, D. G., & Mironov, Y. V. (2017). Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments. Journal of Cluster Science, 28(6), 3103-3114. https://doi.org/10.1007/s10876-017-1276-z

Vancouver

Litvinova YM, Gayfulin YM, Bogomyakov AS, Samsonenko DG, Mironov YV. Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments. Journal of Cluster Science. 2017 Nov 1;28(6):3103-3114. doi: 10.1007/s10876-017-1276-z

Author

Litvinova, Yulia M. ; Gayfulin, Yakov M. ; Bogomyakov, Artem S. et al. / Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments. In: Journal of Cluster Science. 2017 ; Vol. 28, No. 6. pp. 3103-3114.

BibTeX

@article{f58d2570d3f0448f8c1dd9fb21d30fd3,
title = "Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments",
abstract = "Three new polymeric compounds of general formula {[Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2][Re4Te4(CN)12]}·H2O (Ln = Dy, Ho, Er) were obtained by self-assembly reaction of [Re4Te4(CN)12]4– cluster anions, Ln3+ cations and 1,10-phenthroline (phen) in a solvothermal conditions. Single-crystal X-Ray diffraction showed that structure of compounds consist of non-charged ladder-type chains formed by [Re4Te4(CN)12]4− cluster anions and dimeric cationic complexes [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+. Chains are packed parallel and linked with each other by a system of hydrogen bonds. The magnetic susceptibility of compounds is determined by exchange coupled Ln3+ ions in dimeric cationic fragments. The anisotropy effects take place and cause non-linear field dependencies of magnetization for the complexes.",
keywords = "Coordination polymer, Crystal structure, Lanthanides, Magnetic properties, Rhenium cluster, LANTHANIDE LUMINESCENCE, DESIGN, CRYSTAL-STRUCTURE, COMPLEXES, CATIONS, FRAMEWORKS, TE, SE, GD",
author = "Litvinova, {Yulia M.} and Gayfulin, {Yakov M.} and Bogomyakov, {Artem S.} and Samsonenko, {Denis G.} and Mironov, {Yuri V.}",
note = "Publisher Copyright: {\textcopyright} 2017, Springer Science+Business Media, LLC.",
year = "2017",
month = nov,
day = "1",
doi = "10.1007/s10876-017-1276-z",
language = "English",
volume = "28",
pages = "3103--3114",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "6",

}

RIS

TY - JOUR

T1 - Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments

AU - Litvinova, Yulia M.

AU - Gayfulin, Yakov M.

AU - Bogomyakov, Artem S.

AU - Samsonenko, Denis G.

AU - Mironov, Yuri V.

N1 - Publisher Copyright: © 2017, Springer Science+Business Media, LLC.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - Three new polymeric compounds of general formula {[Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2][Re4Te4(CN)12]}·H2O (Ln = Dy, Ho, Er) were obtained by self-assembly reaction of [Re4Te4(CN)12]4– cluster anions, Ln3+ cations and 1,10-phenthroline (phen) in a solvothermal conditions. Single-crystal X-Ray diffraction showed that structure of compounds consist of non-charged ladder-type chains formed by [Re4Te4(CN)12]4− cluster anions and dimeric cationic complexes [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+. Chains are packed parallel and linked with each other by a system of hydrogen bonds. The magnetic susceptibility of compounds is determined by exchange coupled Ln3+ ions in dimeric cationic fragments. The anisotropy effects take place and cause non-linear field dependencies of magnetization for the complexes.

AB - Three new polymeric compounds of general formula {[Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2][Re4Te4(CN)12]}·H2O (Ln = Dy, Ho, Er) were obtained by self-assembly reaction of [Re4Te4(CN)12]4– cluster anions, Ln3+ cations and 1,10-phenthroline (phen) in a solvothermal conditions. Single-crystal X-Ray diffraction showed that structure of compounds consist of non-charged ladder-type chains formed by [Re4Te4(CN)12]4− cluster anions and dimeric cationic complexes [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+. Chains are packed parallel and linked with each other by a system of hydrogen bonds. The magnetic susceptibility of compounds is determined by exchange coupled Ln3+ ions in dimeric cationic fragments. The anisotropy effects take place and cause non-linear field dependencies of magnetization for the complexes.

KW - Coordination polymer

KW - Crystal structure

KW - Lanthanides

KW - Magnetic properties

KW - Rhenium cluster

KW - LANTHANIDE LUMINESCENCE

KW - DESIGN

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - CATIONS

KW - FRAMEWORKS

KW - TE

KW - SE

KW - GD

UR - http://www.scopus.com/inward/record.url?scp=85026480301&partnerID=8YFLogxK

U2 - 10.1007/s10876-017-1276-z

DO - 10.1007/s10876-017-1276-z

M3 - Article

AN - SCOPUS:85026480301

VL - 28

SP - 3103

EP - 3114

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 6

ER -

ID: 9872662