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Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine. / Artem’ev, A. V.; Beresin, A. S.; Bagryanskaya, I. Yu.

In: Journal of Structural Chemistry, Vol. 60, No. 6, 01.06.2019, p. 967-971.

Research output: Contribution to journal › Article › peer-review

Harvard

Artem’ev, AV, Beresin, AS & Bagryanskaya, IY 2019, 'Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine', Journal of Structural Chemistry, vol. 60, no. 6, pp. 967-971. https://doi.org/10.1134/S0022476619060118

APA

Artem’ev, A. V., Beresin, A. S., & Bagryanskaya, I. Y. (2019). Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine. Journal of Structural Chemistry, 60(6), 967-971. https://doi.org/10.1134/S0022476619060118

Vancouver

Artem’ev AV, Beresin AS, Bagryanskaya IY. Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine. Journal of Structural Chemistry. 2019 Jun 1;60(6):967-971. doi: 10.1134/S0022476619060118

Author

Artem’ev, A. V. ; Beresin, A. S. ; Bagryanskaya, I. Yu. / Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine. In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 6. pp. 967-971.

BibTeX

@article{a259c28d251a4764a7bcc63d1e5546e1,
title = "Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine",
abstract = "Reaction of 2-(methylthio)pyrazine (L) with CuI (MeCN, r.t.) results in formation of iodide-bridged complex [Cu2(μ2-I)2L4], wherein Cu⋯Cu contact of 2.6351(4) {\AA} is observed. The each metal atom of the [Cu2(μ2-I)2] core is coordinated by the two ligands via 4-pyrazyl nitrogen atoms. In the solid state at room temperature, the complex obtained emits an orange photoluminescence (λmax = 600 nm) with the average lifetime of 1.66 μs and quantum yield of 17%.",
keywords = "copper(I), crystal structure, photoluminescence, pyrazines, sulfide ligands, COORDINATION-COMPOUNDS, N-DONOR, CRYSTAL-STRUCTURES, COPPER(I) IODIDE",
author = "Artem{\textquoteright}ev, {A. V.} and Beresin, {A. S.} and Bagryanskaya, {I. Yu}",
year = "2019",
month = jun,
day = "1",
doi = "10.1134/S0022476619060118",
language = "English",
volume = "60",
pages = "967--971",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Synthesis, Structure and Emission Properties of [Cu2(μ2-I)2L4] Complex Based on 2-(Methylthio)Pyrazine

AU - Artem’ev, A. V.

AU - Beresin, A. S.

AU - Bagryanskaya, I. Yu

PY - 2019/6/1

Y1 - 2019/6/1

N2 - Reaction of 2-(methylthio)pyrazine (L) with CuI (MeCN, r.t.) results in formation of iodide-bridged complex [Cu2(μ2-I)2L4], wherein Cu⋯Cu contact of 2.6351(4) Å is observed. The each metal atom of the [Cu2(μ2-I)2] core is coordinated by the two ligands via 4-pyrazyl nitrogen atoms. In the solid state at room temperature, the complex obtained emits an orange photoluminescence (λmax = 600 nm) with the average lifetime of 1.66 μs and quantum yield of 17%.

AB - Reaction of 2-(methylthio)pyrazine (L) with CuI (MeCN, r.t.) results in formation of iodide-bridged complex [Cu2(μ2-I)2L4], wherein Cu⋯Cu contact of 2.6351(4) Å is observed. The each metal atom of the [Cu2(μ2-I)2] core is coordinated by the two ligands via 4-pyrazyl nitrogen atoms. In the solid state at room temperature, the complex obtained emits an orange photoluminescence (λmax = 600 nm) with the average lifetime of 1.66 μs and quantum yield of 17%.

KW - copper(I)

KW - crystal structure

KW - photoluminescence

KW - pyrazines

KW - sulfide ligands

KW - COORDINATION-COMPOUNDS

KW - N-DONOR

KW - CRYSTAL-STRUCTURES

KW - COPPER(I) IODIDE

UR - http://www.scopus.com/inward/record.url?scp=85068769287&partnerID=8YFLogxK

U2 - 10.1134/S0022476619060118

DO - 10.1134/S0022476619060118

M3 - Article

AN - SCOPUS:85068769287

VL - 60

SP - 967

EP - 971

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 20838572