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Synthesis, crystal structure and thermal stability of 1D linear silver(I) coordination polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane. / Semitut, Evgeny; Komarov, Vladislav; Sukhikh, Taisiya et al.

In: Crystals, Vol. 6, No. 11, 138, 11.2016.

Research output: Contribution to journal › Article › peer-review

Harvard

Semitut, E, Komarov, V, Sukhikh, T, Filatov, E & Potapov, A 2016, 'Synthesis, crystal structure and thermal stability of 1D linear silver(I) coordination polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane', Crystals, vol. 6, no. 11, 138. https://doi.org/10.3390/cryst6110138

APA

Semitut, E., Komarov, V., Sukhikh, T., Filatov, E., & Potapov, A. (2016). Synthesis, crystal structure and thermal stability of 1D linear silver(I) coordination polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane. Crystals, 6(11), [138]. https://doi.org/10.3390/cryst6110138

Vancouver

Semitut E, Komarov V, Sukhikh T, Filatov E, Potapov A. Synthesis, crystal structure and thermal stability of 1D linear silver(I) coordination polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane. Crystals. 2016 Nov;6(11):138. doi: 10.3390/cryst6110138

Author

Semitut, Evgeny ; Komarov, Vladislav ; Sukhikh, Taisiya et al. / Synthesis, crystal structure and thermal stability of 1D linear silver(I) coordination polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane. In: Crystals. 2016 ; Vol. 6, No. 11.

BibTeX

@article{12f4fa1d77e845528723b2083bf2faba,
title = "Synthesis, crystal structure and thermal stability of 1D linear silver(I) coordination polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane",
abstract = "Two new linear silver(I) nitrate coordination polymers with bitopic ligand 1,1,2,2-tetra(pyrazol-1-yl)ethane were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction and thermal analysis. Silver coordination polymers demonstrated a yellow emission near 500 nm upon excitation at 360 nm. Crystal structures of coordination polymers were determined and structural peculiarities are discussed. In both of the structures, silver ions are connected via bridging ligand molecules to form polymeric chains with a five-atomic environment. The coordination environment of the central atom corresponds to a distorted trigonal bipyramid with two N atoms of different ligands in apical positions. The Ag-N bond distances vary in a wide range of 2.31-2.62 {\AA}, giving strongly distorted metallacycles. Thermolysis of coordination polymers in reductive atmosphere (H2/He) leads to the formation of silver nanoparticles with a narrow size distribution.",
keywords = "Bitopic ligand, Coordination polymer, Crystal structure, Luminescence, Pyrazole, Silver, Silver nanoparticles, Thermal analysis",
author = "Evgeny Semitut and Vladislav Komarov and Taisiya Sukhikh and Evgeny Filatov and Andrei Potapov",
year = "2016",
month = nov,
doi = "10.3390/cryst6110138",
language = "English",
volume = "6",
journal = "Crystals",
issn = "2073-4352",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "11",

}

RIS

TY - JOUR

T1 - Synthesis, crystal structure and thermal stability of 1D linear silver(I) coordination polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane

AU - Semitut, Evgeny

AU - Komarov, Vladislav

AU - Sukhikh, Taisiya

AU - Filatov, Evgeny

AU - Potapov, Andrei

PY - 2016/11

Y1 - 2016/11

N2 - Two new linear silver(I) nitrate coordination polymers with bitopic ligand 1,1,2,2-tetra(pyrazol-1-yl)ethane were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction and thermal analysis. Silver coordination polymers demonstrated a yellow emission near 500 nm upon excitation at 360 nm. Crystal structures of coordination polymers were determined and structural peculiarities are discussed. In both of the structures, silver ions are connected via bridging ligand molecules to form polymeric chains with a five-atomic environment. The coordination environment of the central atom corresponds to a distorted trigonal bipyramid with two N atoms of different ligands in apical positions. The Ag-N bond distances vary in a wide range of 2.31-2.62 Å, giving strongly distorted metallacycles. Thermolysis of coordination polymers in reductive atmosphere (H2/He) leads to the formation of silver nanoparticles with a narrow size distribution.

AB - Two new linear silver(I) nitrate coordination polymers with bitopic ligand 1,1,2,2-tetra(pyrazol-1-yl)ethane were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction and thermal analysis. Silver coordination polymers demonstrated a yellow emission near 500 nm upon excitation at 360 nm. Crystal structures of coordination polymers were determined and structural peculiarities are discussed. In both of the structures, silver ions are connected via bridging ligand molecules to form polymeric chains with a five-atomic environment. The coordination environment of the central atom corresponds to a distorted trigonal bipyramid with two N atoms of different ligands in apical positions. The Ag-N bond distances vary in a wide range of 2.31-2.62 Å, giving strongly distorted metallacycles. Thermolysis of coordination polymers in reductive atmosphere (H2/He) leads to the formation of silver nanoparticles with a narrow size distribution.

KW - Bitopic ligand

KW - Coordination polymer

KW - Crystal structure

KW - Luminescence

KW - Pyrazole

KW - Silver

KW - Silver nanoparticles

KW - Thermal analysis

UR - http://www.scopus.com/inward/record.url?scp=84995676861&partnerID=8YFLogxK

U2 - 10.3390/cryst6110138

DO - 10.3390/cryst6110138

M3 - Article

AN - SCOPUS:84995676861

VL - 6

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 11

M1 - 138

ER -

ID: 25398285