Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes

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Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes. / Bashirov, D. A.; Kolybalov, D. S.; Sukhikh, T. S. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 4, 01.04.2020, p. 550-558.

Research output: Contribution to journal › Article › peer-review

Author

Bashirov, D. A. ; Kolybalov, D. S. ; Sukhikh, T. S. et al. / Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 4. pp. 550-558.

BibTeX

@article{94a80871ec714c189db04f534684e629,

title = "Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes",

abstract = "By the interaction of TmCl3 with KFormDipp (FormDipp = N,N′-bis(2,6-diisopropylphenyl)-formamidinate) [Tm(FormDipp)2Cl(THF)] (1) and [KTm(FormDipp)2Cl2]2(2) complexes are obtained. The reaction of 1 with potassium thiophenolate is studied. Its product is found to be [Tm(FormDipp)2(SPh)(THF)] complex (3). The structure of all prepared compounds is determined by single crystal X-ray diffraction of the following solid phases: 1a (P-1) and 1b (P21/n) phases being two solvent-free polymorphs for complex 1; 2·0.5C7H8> and 3·C7H8 phases containing solvate toluene molecules for complexes 2 and 3.",

keywords = "amidinates, coordinate compounds, crystal structure, formamidinates, lanthanides, synthesis, thulium, CLUSTERS, REACTIVITY, CHEMISTRY",

author = "Bashirov, {D. A.} and Kolybalov, {D. S.} and Sukhikh, {T. S.} and Konchenko, {S. N.}",

year = "2020",

month = apr,

day = "1",

doi = "10.1134/S0022476620040071",

language = "English",

volume = "61",

pages = "550--558",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "4",

}

RIS

TY - JOUR

T1 - Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes

AU - Bashirov, D. A.

AU - Kolybalov, D. S.

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

PY - 2020/4/1

Y1 - 2020/4/1

N2 - By the interaction of TmCl3 with KFormDipp (FormDipp = N,N′-bis(2,6-diisopropylphenyl)-formamidinate) [Tm(FormDipp)2Cl(THF)] (1) and [KTm(FormDipp)2Cl2]2(2) complexes are obtained. The reaction of 1 with potassium thiophenolate is studied. Its product is found to be [Tm(FormDipp)2(SPh)(THF)] complex (3). The structure of all prepared compounds is determined by single crystal X-ray diffraction of the following solid phases: 1a (P-1) and 1b (P21/n) phases being two solvent-free polymorphs for complex 1; 2·0.5C7H8> and 3·C7H8 phases containing solvate toluene molecules for complexes 2 and 3.

AB - By the interaction of TmCl3 with KFormDipp (FormDipp = N,N′-bis(2,6-diisopropylphenyl)-formamidinate) [Tm(FormDipp)2Cl(THF)] (1) and [KTm(FormDipp)2Cl2]2(2) complexes are obtained. The reaction of 1 with potassium thiophenolate is studied. Its product is found to be [Tm(FormDipp)2(SPh)(THF)] complex (3). The structure of all prepared compounds is determined by single crystal X-ray diffraction of the following solid phases: 1a (P-1) and 1b (P21/n) phases being two solvent-free polymorphs for complex 1; 2·0.5C7H8> and 3·C7H8 phases containing solvate toluene molecules for complexes 2 and 3.

KW - amidinates

KW - coordinate compounds

KW - crystal structure

KW - formamidinates

KW - lanthanides

KW - synthesis

KW - thulium

KW - CLUSTERS

KW - REACTIVITY

KW - CHEMISTRY

UR - http://www.scopus.com/inward/record.url?scp=85088636181&partnerID=8YFLogxK

U2 - 10.1134/S0022476620040071

DO - 10.1134/S0022476620040071

M3 - Article

AN - SCOPUS:85088636181

VL - 61

SP - 550

EP - 558

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 24867817