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Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+. / Pronin, A. S.; Smolentsev, A. I.; Mironov, Yu V.

In: Journal of Structural Chemistry, Vol. 61, No. 1, 01.01.2020, p. 95-100.

Research output: Contribution to journal › Article › peer-review

Harvard

Pronin, AS, Smolentsev, AI & Mironov, YV 2020, 'Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+', Journal of Structural Chemistry, vol. 61, no. 1, pp. 95-100. https://doi.org/10.1134/S0022476620010102

APA

Pronin, A. S., Smolentsev, A. I., & Mironov, Y. V. (2020). Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+. Journal of Structural Chemistry, 61(1), 95-100. https://doi.org/10.1134/S0022476620010102

Vancouver

Pronin AS, Smolentsev AI, Mironov YV. Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+. Journal of Structural Chemistry. 2020 Jan 1;61(1):95-100. doi: 10.1134/S0022476620010102

Author

Pronin, A. S. ; Smolentsev, A. I. ; Mironov, Yu V. / Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 1. pp. 95-100.

BibTeX

@article{57d4caab7a2e45998a701960eef68b35,
title = "Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+",
abstract = "A novel mixed-ligand cluster complex of the composition K7[{Re4As0.75(AsO)2,25Te}(CN)12]·9H2O is obtained by a high-temperature reaction of ReI3, As, and Te with KCN followed by recrystallization from an aqueous solution. The structure of the complex is determined by X-ray crystallography. The compound crystallizes in the triclinic crystal system, space group P1 ¯ with unit cell parameters a= 11.6777(4) {\AA}, b = 11.8627(3) {\AA}, c = 16.5280(5) {\AA}, α = 95.3590(10)°, β = 92.8170(10)°, γ = 117.9830(10)°, V = 2001.80(10) {\AA}3, Z = 2. The crystal structure consists of K+ cations, the cluster [{Re4As0.75(AsO)2.25Te}(CN)12]7− anion, and nine solvate H2O molecules.",
keywords = "arsenic, cluster complexes, crystal structure, mixed-ligand complexes, rhenium, tellurium, SE",
author = "Pronin, {A. S.} and Smolentsev, {A. I.} and Mironov, {Yu V.}",
year = "2020",
month = jan,
day = "1",
doi = "10.1134/S0022476620010102",
language = "English",
volume = "61",
pages = "95--100",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

RIS

TY - JOUR

T1 - Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+

AU - Pronin, A. S.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

PY - 2020/1/1

Y1 - 2020/1/1

N2 - A novel mixed-ligand cluster complex of the composition K7[{Re4As0.75(AsO)2,25Te}(CN)12]·9H2O is obtained by a high-temperature reaction of ReI3, As, and Te with KCN followed by recrystallization from an aqueous solution. The structure of the complex is determined by X-ray crystallography. The compound crystallizes in the triclinic crystal system, space group P1 ¯ with unit cell parameters a= 11.6777(4) Å, b = 11.8627(3) Å, c = 16.5280(5) Å, α = 95.3590(10)°, β = 92.8170(10)°, γ = 117.9830(10)°, V = 2001.80(10) Å3, Z = 2. The crystal structure consists of K+ cations, the cluster [{Re4As0.75(AsO)2.25Te}(CN)12]7− anion, and nine solvate H2O molecules.

AB - A novel mixed-ligand cluster complex of the composition K7[{Re4As0.75(AsO)2,25Te}(CN)12]·9H2O is obtained by a high-temperature reaction of ReI3, As, and Te with KCN followed by recrystallization from an aqueous solution. The structure of the complex is determined by X-ray crystallography. The compound crystallizes in the triclinic crystal system, space group P1 ¯ with unit cell parameters a= 11.6777(4) Å, b = 11.8627(3) Å, c = 16.5280(5) Å, α = 95.3590(10)°, β = 92.8170(10)°, γ = 117.9830(10)°, V = 2001.80(10) Å3, Z = 2. The crystal structure consists of K+ cations, the cluster [{Re4As0.75(AsO)2.25Te}(CN)12]7− anion, and nine solvate H2O molecules.

KW - arsenic

KW - cluster complexes

KW - crystal structure

KW - mixed-ligand complexes

KW - rhenium

KW - tellurium

KW - SE

UR - http://www.scopus.com/inward/record.url?scp=85087948249&partnerID=8YFLogxK

U2 - 10.1134/S0022476620010102

DO - 10.1134/S0022476620010102

M3 - Article

AN - SCOPUS:85087948249

VL - 61

SP - 95

EP - 100

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 24769052