Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+. / Pronin, A. S.; Smolentsev, A. I.; Mironov, Yu V.
в: Journal of Structural Chemistry, Том 61, № 1, 01.01.2020, стр. 95-100.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+
AU - Pronin, A. S.
AU - Smolentsev, A. I.
AU - Mironov, Yu V.
PY - 2020/1/1
Y1 - 2020/1/1
N2 - A novel mixed-ligand cluster complex of the composition K7[{Re4As0.75(AsO)2,25Te}(CN)12]·9H2O is obtained by a high-temperature reaction of ReI3, As, and Te with KCN followed by recrystallization from an aqueous solution. The structure of the complex is determined by X-ray crystallography. The compound crystallizes in the triclinic crystal system, space group P1 ¯ with unit cell parameters a= 11.6777(4) Å, b = 11.8627(3) Å, c = 16.5280(5) Å, α = 95.3590(10)°, β = 92.8170(10)°, γ = 117.9830(10)°, V = 2001.80(10) Å3, Z = 2. The crystal structure consists of K+ cations, the cluster [{Re4As0.75(AsO)2.25Te}(CN)12]7− anion, and nine solvate H2O molecules.
AB - A novel mixed-ligand cluster complex of the composition K7[{Re4As0.75(AsO)2,25Te}(CN)12]·9H2O is obtained by a high-temperature reaction of ReI3, As, and Te with KCN followed by recrystallization from an aqueous solution. The structure of the complex is determined by X-ray crystallography. The compound crystallizes in the triclinic crystal system, space group P1 ¯ with unit cell parameters a= 11.6777(4) Å, b = 11.8627(3) Å, c = 16.5280(5) Å, α = 95.3590(10)°, β = 92.8170(10)°, γ = 117.9830(10)°, V = 2001.80(10) Å3, Z = 2. The crystal structure consists of K+ cations, the cluster [{Re4As0.75(AsO)2.25Te}(CN)12]7− anion, and nine solvate H2O molecules.
KW - arsenic
KW - cluster complexes
KW - crystal structure
KW - mixed-ligand complexes
KW - rhenium
KW - tellurium
KW - SE
UR - http://www.scopus.com/inward/record.url?scp=85087948249&partnerID=8YFLogxK
U2 - 10.1134/S0022476620010102
DO - 10.1134/S0022476620010102
M3 - Article
AN - SCOPUS:85087948249
VL - 61
SP - 95
EP - 100
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 1
ER -
ID: 24769052