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Synthesis and magnetic and cytotoxic properties of copper(II) halide complexes with 1,2,4-triazolo[1,5- : A] benzimidazoles. / Lavrenova, L. G.; Kuz'menko, T. A.; Ivanova, A. D. et al.

In: New Journal of Chemistry, Vol. 41, No. 11, 07.06.2017, p. 4341-4347.

Research output: Contribution to journal › Article › peer-review

Harvard

Lavrenova, LG, Kuz'menko, TA, Ivanova, AD, Smolentsev, AI, Komarov, VY, Bogomyakov, AS, Sheludyakova, LA & Vorontsova, EV 2017, 'Synthesis and magnetic and cytotoxic properties of copper(II) halide complexes with 1,2,4-triazolo[1,5-: A] benzimidazoles', New Journal of Chemistry, vol. 41, no. 11, pp. 4341-4347. https://doi.org/10.1039/c7nj00533d

APA

Lavrenova, L. G., Kuz'menko, T. A., Ivanova, A. D., Smolentsev, A. I., Komarov, V. Y., Bogomyakov, A. S., Sheludyakova, L. A., & Vorontsova, E. V. (2017). Synthesis and magnetic and cytotoxic properties of copper(II) halide complexes with 1,2,4-triazolo[1,5-: A] benzimidazoles. New Journal of Chemistry, 41(11), 4341-4347. https://doi.org/10.1039/c7nj00533d

Vancouver

Lavrenova LG, Kuz'menko TA, Ivanova AD, Smolentsev AI, Komarov VY, Bogomyakov AS et al. Synthesis and magnetic and cytotoxic properties of copper(II) halide complexes with 1,2,4-triazolo[1,5-: A] benzimidazoles. New Journal of Chemistry. 2017 Jun 7;41(11):4341-4347. doi: 10.1039/c7nj00533d

Author

Lavrenova, L. G. ; Kuz'menko, T. A. ; Ivanova, A. D. et al. / Synthesis and magnetic and cytotoxic properties of copper(II) halide complexes with 1,2,4-triazolo[1,5- : A] benzimidazoles. In: New Journal of Chemistry. 2017 ; Vol. 41, No. 11. pp. 4341-4347.

BibTeX

@article{8ea6345c657643a2a7bbe04d5045d07c,
title = "Synthesis and magnetic and cytotoxic properties of copper(II) halide complexes with 1,2,4-triazolo[1,5-: A] benzimidazoles",
abstract = "Coordination compounds based on copper(ii) halides with 4H-1,2,4-triazolo[1,5-a]benzimidazole (L1), 3-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L2), and 4-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L3) with the compositions [Cu(L1)2(Hal)2]·nH2O (Hal = Cl-, n = 0.5 (I) Br-, n = 1 (II)); [Cu(L2)2Cl2] (III), [Cu(L3)2Cl2] (IV) and [Cu(L3)2Br2(H2O)]·2H2O (V) were synthesized. The compounds were characterized using X-ray diffraction, UV-Vis spectroscopy (diffuse reflectance spectra), infrared spectroscopy, and static magnetic susceptibility measurements. By means of X-ray diffraction structural analysis, crystal structures were determined for the [Cu(L3)2(Hal)2(H2O)]·2H2O complexes, where Hal = Cl- (IVa) or Br- (V). Cytotoxic effects of the complexes and ligands on the cell line Hep-2 were then studied, and we found that the copper(ii) complex with ligands L1-L3 leads to a considerable enhancement of cytotoxicity.",
keywords = "DERIVATIVES",
author = "Lavrenova, {L. G.} and Kuz'menko, {T. A.} and Ivanova, {A. D.} and Smolentsev, {A. I.} and Komarov, {V. Yu} and Bogomyakov, {A. S.} and Sheludyakova, {L. A.} and Vorontsova, {E. V.}",
year = "2017",
month = jun,
day = "7",
doi = "10.1039/c7nj00533d",
language = "English",
volume = "41",
pages = "4341--4347",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "11",

}

RIS

TY - JOUR

T1 - Synthesis and magnetic and cytotoxic properties of copper(II) halide complexes with 1,2,4-triazolo[1,5-

T2 - A] benzimidazoles

AU - Lavrenova, L. G.

AU - Kuz'menko, T. A.

AU - Ivanova, A. D.

AU - Smolentsev, A. I.

AU - Komarov, V. Yu

AU - Bogomyakov, A. S.

AU - Sheludyakova, L. A.

AU - Vorontsova, E. V.

PY - 2017/6/7

Y1 - 2017/6/7

N2 - Coordination compounds based on copper(ii) halides with 4H-1,2,4-triazolo[1,5-a]benzimidazole (L1), 3-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L2), and 4-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L3) with the compositions [Cu(L1)2(Hal)2]·nH2O (Hal = Cl-, n = 0.5 (I) Br-, n = 1 (II)); [Cu(L2)2Cl2] (III), [Cu(L3)2Cl2] (IV) and [Cu(L3)2Br2(H2O)]·2H2O (V) were synthesized. The compounds were characterized using X-ray diffraction, UV-Vis spectroscopy (diffuse reflectance spectra), infrared spectroscopy, and static magnetic susceptibility measurements. By means of X-ray diffraction structural analysis, crystal structures were determined for the [Cu(L3)2(Hal)2(H2O)]·2H2O complexes, where Hal = Cl- (IVa) or Br- (V). Cytotoxic effects of the complexes and ligands on the cell line Hep-2 were then studied, and we found that the copper(ii) complex with ligands L1-L3 leads to a considerable enhancement of cytotoxicity.

AB - Coordination compounds based on copper(ii) halides with 4H-1,2,4-triazolo[1,5-a]benzimidazole (L1), 3-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L2), and 4-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L3) with the compositions [Cu(L1)2(Hal)2]·nH2O (Hal = Cl-, n = 0.5 (I) Br-, n = 1 (II)); [Cu(L2)2Cl2] (III), [Cu(L3)2Cl2] (IV) and [Cu(L3)2Br2(H2O)]·2H2O (V) were synthesized. The compounds were characterized using X-ray diffraction, UV-Vis spectroscopy (diffuse reflectance spectra), infrared spectroscopy, and static magnetic susceptibility measurements. By means of X-ray diffraction structural analysis, crystal structures were determined for the [Cu(L3)2(Hal)2(H2O)]·2H2O complexes, where Hal = Cl- (IVa) or Br- (V). Cytotoxic effects of the complexes and ligands on the cell line Hep-2 were then studied, and we found that the copper(ii) complex with ligands L1-L3 leads to a considerable enhancement of cytotoxicity.

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85021633384&partnerID=8YFLogxK

U2 - 10.1039/c7nj00533d

DO - 10.1039/c7nj00533d

M3 - Article

AN - SCOPUS:85021633384

VL - 41

SP - 4341

EP - 4347

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 11

ER -

ID: 10098320