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Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole. / Konovalov, Dmitriy I.; Ivanov, Anton A.; Vorotnikov, Yuri A. et al.

In: Inorganica Chimica Acta, Vol. 498, 119128, 01.12.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Konovalov, DI, Ivanov, AA, Vorotnikov, YA, Brylev, KA, Eltsov, IV, Kuratieva, NV, Kitamura, N, Mironov, YV & Shestopalov, MA 2019, 'Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole', Inorganica Chimica Acta, vol. 498, 119128. https://doi.org/10.1016/j.ica.2019.119128

APA

Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Brylev, K. A., Eltsov, I. V., Kuratieva, N. V., Kitamura, N., Mironov, Y. V., & Shestopalov, M. A. (2019). Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole. Inorganica Chimica Acta, 498, [119128]. https://doi.org/10.1016/j.ica.2019.119128

Vancouver

Konovalov DI, Ivanov AA, Vorotnikov YA, Brylev KA, Eltsov IV, Kuratieva NV et al. Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole. Inorganica Chimica Acta. 2019 Dec 1;498:119128. doi: 10.1016/j.ica.2019.119128

Author

Konovalov, Dmitriy I. ; Ivanov, Anton A. ; Vorotnikov, Yuri A. et al. / Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole. In: Inorganica Chimica Acta. 2019 ; Vol. 498.

BibTeX

@article{cdd87c092e19403ba8ef9ac6ab08a384,
title = "Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole",
abstract = "Interaction of cluster anions [{Re6Q8}X6]4−/3− (Q = S or Se; X = Cl, Br or I) with molten pro-ligands – pyrazole (pzH) and 3,5-dimethylpyrazole (3,5-Me2pzH) has led to the formation of cationic apically homoleptic cluster complexes [{Re6Q8}L6]2+ (L = pzH or 3,5-Me2pzH). All new compounds were characterized by a set of physicochemical properties such as X-ray diffraction analyses on crystals and powders, FTIR and NMR spectroscopies. Synthesis of the complete series of pyrazole complexes and finishing the earlier series of 3,5-dimethylpyrazole complexes with different halogens in addition to the previously described [{Re6Q8}(3,5-Me2pzH)6]Br2·2(3,5-Me2pzH) (Q = S, Se) allowed us to study dependence of luminescence properties on the nature of the inner or outer ligands as well as counterions in detail.",
keywords = "Crystal structure, Luminescence, Pyrazole, Rhenium cluster, CRYSTAL-STRUCTURE, Q=S, COMPLEXES, CL, HEXARHENIUM(III) CLUSTERS, FAMILY, BR, SE, LIGANDS, METAL",
author = "Konovalov, {Dmitriy I.} and Ivanov, {Anton A.} and Vorotnikov, {Yuri A.} and Brylev, {Konstantin A.} and Eltsov, {Ilia V.} and Kuratieva, {Natalia V.} and Noboru Kitamura and Mironov, {Yuri V.} and Shestopalov, {Michael A.}",
note = "Funding Information: This research was supported by the Russian Foundation for Basic Research (Grant No. 18-33-00025 ). Also, NIIC team thanks the Ministry of Science and Education of the Russian Federation. Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",
year = "2019",
month = dec,
day = "1",
doi = "10.1016/j.ica.2019.119128",
language = "English",
volume = "498",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole

AU - Konovalov, Dmitriy I.

AU - Ivanov, Anton A.

AU - Vorotnikov, Yuri A.

AU - Brylev, Konstantin A.

AU - Eltsov, Ilia V.

AU - Kuratieva, Natalia V.

AU - Kitamura, Noboru

AU - Mironov, Yuri V.

AU - Shestopalov, Michael A.

N1 - Funding Information: This research was supported by the Russian Foundation for Basic Research (Grant No. 18-33-00025 ). Also, NIIC team thanks the Ministry of Science and Education of the Russian Federation. Publisher Copyright: © 2019 Elsevier B.V.

PY - 2019/12/1

Y1 - 2019/12/1

N2 - Interaction of cluster anions [{Re6Q8}X6]4−/3− (Q = S or Se; X = Cl, Br or I) with molten pro-ligands – pyrazole (pzH) and 3,5-dimethylpyrazole (3,5-Me2pzH) has led to the formation of cationic apically homoleptic cluster complexes [{Re6Q8}L6]2+ (L = pzH or 3,5-Me2pzH). All new compounds were characterized by a set of physicochemical properties such as X-ray diffraction analyses on crystals and powders, FTIR and NMR spectroscopies. Synthesis of the complete series of pyrazole complexes and finishing the earlier series of 3,5-dimethylpyrazole complexes with different halogens in addition to the previously described [{Re6Q8}(3,5-Me2pzH)6]Br2·2(3,5-Me2pzH) (Q = S, Se) allowed us to study dependence of luminescence properties on the nature of the inner or outer ligands as well as counterions in detail.

AB - Interaction of cluster anions [{Re6Q8}X6]4−/3− (Q = S or Se; X = Cl, Br or I) with molten pro-ligands – pyrazole (pzH) and 3,5-dimethylpyrazole (3,5-Me2pzH) has led to the formation of cationic apically homoleptic cluster complexes [{Re6Q8}L6]2+ (L = pzH or 3,5-Me2pzH). All new compounds were characterized by a set of physicochemical properties such as X-ray diffraction analyses on crystals and powders, FTIR and NMR spectroscopies. Synthesis of the complete series of pyrazole complexes and finishing the earlier series of 3,5-dimethylpyrazole complexes with different halogens in addition to the previously described [{Re6Q8}(3,5-Me2pzH)6]Br2·2(3,5-Me2pzH) (Q = S, Se) allowed us to study dependence of luminescence properties on the nature of the inner or outer ligands as well as counterions in detail.

KW - Crystal structure

KW - Luminescence

KW - Pyrazole

KW - Rhenium cluster

KW - CRYSTAL-STRUCTURE

KW - Q=S

KW - COMPLEXES

KW - CL

KW - HEXARHENIUM(III) CLUSTERS

KW - FAMILY

KW - BR

KW - SE

KW - LIGANDS

KW - METAL

UR - http://www.scopus.com/inward/record.url?scp=85072180716&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2019.119128

DO - 10.1016/j.ica.2019.119128

M3 - Article

AN - SCOPUS:85072180716

VL - 498

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 119128

ER -

ID: 21538876