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Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand. / Shmelev, N. Yu; Gongola, M. I.; Malysheva, S. F. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 47, No. 3, 03.2021, p. 209-218.

Research output: Contribution to journal › Article › peer-review

Harvard

Shmelev, NY, Gongola, MI, Malysheva, SF, Belogorlova, NA, Artem’ev, AV, Fomenko, YS, Komarov, VY, Sopov, KV, Kompan’kov, NB, Sheven’, DG, Sokolov, MN & Gushchin, AL 2021, 'Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 3, pp. 209-218. https://doi.org/10.1134/S1070328421030040

APA

Shmelev, N. Y., Gongola, M. I., Malysheva, S. F., Belogorlova, N. A., Artem’ev, A. V., Fomenko, Y. S., Komarov, V. Y., Sopov, K. V., Kompan’kov, N. B., Sheven’, D. G., Sokolov, M. N., & Gushchin, A. L. (2021). Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 47(3), 209-218. https://doi.org/10.1134/S1070328421030040

Vancouver

Shmelev NY, Gongola MI, Malysheva SF, Belogorlova NA, Artem’ev AV, Fomenko YS et al. Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 Mar;47(3):209-218. doi: 10.1134/S1070328421030040

Author

Shmelev, N. Yu ; Gongola, M. I. ; Malysheva, S. F. et al. / Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 ; Vol. 47, No. 3. pp. 209-218.

BibTeX

@article{b14ed795bd844064870616c7cec64e3a,
title = "Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand",
abstract = "The reaction of [Mo3S4(Tu)8(H2O)]Cl4·4H2O (Tu is thiourea) with (PhCH2CH2)2-PCH2CH2SeC5H11) (PSe) followed by purification on a chromatographic column packed with silica gel using a saturated solution of KPF6 in acetone as an eluent results in the formation of [Mo3S4Cl3(PSe)3]PF6 (I) in a yield of 44%. Compound I is characterized by X-ray diffraction analysis, 1H, 31P{1H}, and 77Se NMR spectroscopy, IR spectroscopy, UV-Vis spectroscopy, cyclic voltammetry, and electrospray ionization mass spectrometry. Several species differed in the coordination mode of three PSe ligands, which can bind to molybdenum via one (phosphorus) or two (phosphorus and selenium) donor atoms, are formed in a solution of compound I at room temperature. This behavior is not observed for the compounds similar in structure with PS ligands of an analogous type. Complex I demonstrates a higher catalytic activity than its analogue with the PS ligand in the reduction of nitrobenzene to aniline under the action of diphenylsilane.",
keywords = "catalytic properties, clusters, crystal structure, hemilabile ligands, molybdenum, phosphine-chalcoethers, synthesis",
author = "Shmelev, {N. Yu} and Gongola, {M. I.} and Malysheva, {S. F.} and Belogorlova, {N. A.} and Artem{\textquoteright}ev, {A. V.} and Fomenko, {Ya S.} and Komarov, {V. Yu} and Sopov, {K. V.} and Kompan{\textquoteright}kov, {N. B.} and Sheven{\textquoteright}, {D. G.} and Sokolov, {M. N.} and Gushchin, {A. L.}",
note = "Funding Information: This work was supported by the Russian Foundation for Basic Research, projects nos. 18-33-20056 and 19-33-90097. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = mar,
doi = "10.1134/S1070328421030040",
language = "English",
volume = "47",
pages = "209--218",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "3",

}

RIS

TY - JOUR

T1 - Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand

AU - Shmelev, N. Yu

AU - Gongola, M. I.

AU - Malysheva, S. F.

AU - Belogorlova, N. A.

AU - Artem’ev, A. V.

AU - Fomenko, Ya S.

AU - Komarov, V. Yu

AU - Sopov, K. V.

AU - Kompan’kov, N. B.

AU - Sheven’, D. G.

AU - Sokolov, M. N.

AU - Gushchin, A. L.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research, projects nos. 18-33-20056 and 19-33-90097. Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/3

Y1 - 2021/3

N2 - The reaction of [Mo3S4(Tu)8(H2O)]Cl4·4H2O (Tu is thiourea) with (PhCH2CH2)2-PCH2CH2SeC5H11) (PSe) followed by purification on a chromatographic column packed with silica gel using a saturated solution of KPF6 in acetone as an eluent results in the formation of [Mo3S4Cl3(PSe)3]PF6 (I) in a yield of 44%. Compound I is characterized by X-ray diffraction analysis, 1H, 31P{1H}, and 77Se NMR spectroscopy, IR spectroscopy, UV-Vis spectroscopy, cyclic voltammetry, and electrospray ionization mass spectrometry. Several species differed in the coordination mode of three PSe ligands, which can bind to molybdenum via one (phosphorus) or two (phosphorus and selenium) donor atoms, are formed in a solution of compound I at room temperature. This behavior is not observed for the compounds similar in structure with PS ligands of an analogous type. Complex I demonstrates a higher catalytic activity than its analogue with the PS ligand in the reduction of nitrobenzene to aniline under the action of diphenylsilane.

AB - The reaction of [Mo3S4(Tu)8(H2O)]Cl4·4H2O (Tu is thiourea) with (PhCH2CH2)2-PCH2CH2SeC5H11) (PSe) followed by purification on a chromatographic column packed with silica gel using a saturated solution of KPF6 in acetone as an eluent results in the formation of [Mo3S4Cl3(PSe)3]PF6 (I) in a yield of 44%. Compound I is characterized by X-ray diffraction analysis, 1H, 31P{1H}, and 77Se NMR spectroscopy, IR spectroscopy, UV-Vis spectroscopy, cyclic voltammetry, and electrospray ionization mass spectrometry. Several species differed in the coordination mode of three PSe ligands, which can bind to molybdenum via one (phosphorus) or two (phosphorus and selenium) donor atoms, are formed in a solution of compound I at room temperature. This behavior is not observed for the compounds similar in structure with PS ligands of an analogous type. Complex I demonstrates a higher catalytic activity than its analogue with the PS ligand in the reduction of nitrobenzene to aniline under the action of diphenylsilane.

KW - catalytic properties

KW - clusters

KW - crystal structure

KW - hemilabile ligands

KW - molybdenum

KW - phosphine-chalcoethers

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=85102925746&partnerID=8YFLogxK

U2 - 10.1134/S1070328421030040

DO - 10.1134/S1070328421030040

M3 - Article

AN - SCOPUS:85102925746

VL - 47

SP - 209

EP - 218

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 3

ER -

ID: 28201965