Research output: Contribution to journal › Article › peer-review
Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives. / Zavakhina, M. S.; Samsonenko, D. G.; Dybtsev, D. N. et al.
In: Russian Chemical Bulletin, Vol. 64, No. 12, 01.12.2015, p. 2908-2913.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives
AU - Zavakhina, M. S.
AU - Samsonenko, D. G.
AU - Dybtsev, D. N.
AU - Argent, S. P.
AU - Blake, A. J.
AU - Schröder, M.
AU - Fedin, V. P.
PY - 2015/12/1
Y1 - 2015/12/1
N2 - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.
AB - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.
KW - chiral complexes
KW - coordination polymers
KW - copper
KW - crystal structure
KW - supramolecular interactions
UR - http://www.scopus.com/inward/record.url?scp=84988422889&partnerID=8YFLogxK
U2 - 10.1007/s11172-015-1246-2
DO - 10.1007/s11172-015-1246-2
M3 - Article
AN - SCOPUS:84988422889
VL - 64
SP - 2908
EP - 2913
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 12
ER -
ID: 25418196