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Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives. / Zavakhina, M. S.; Samsonenko, D. G.; Dybtsev, D. N. et al.

In: Russian Chemical Bulletin, Vol. 64, No. 12, 01.12.2015, p. 2908-2913.

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Zavakhina MS, Samsonenko DG, Dybtsev DN, Argent SP, Blake AJ, Schröder M et al. Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives. Russian Chemical Bulletin. 2015 Dec 1;64(12):2908-2913. doi: 10.1007/s11172-015-1246-2

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@article{8a99f37e020f43aabdca566fd6c9135d,
title = "Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives",
abstract = "Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.",
keywords = "chiral complexes, coordination polymers, copper, crystal structure, supramolecular interactions",
author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Argent, {S. P.} and Blake, {A. J.} and M. Schr{\"o}der and Fedin, {V. P.}",
year = "2015",
month = dec,
day = "1",
doi = "10.1007/s11172-015-1246-2",
language = "English",
volume = "64",
pages = "2908--2913",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "12",

}

RIS

TY - JOUR

T1 - Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Argent, S. P.

AU - Blake, A. J.

AU - Schröder, M.

AU - Fedin, V. P.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

AB - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

KW - chiral complexes

KW - coordination polymers

KW - copper

KW - crystal structure

KW - supramolecular interactions

UR - http://www.scopus.com/inward/record.url?scp=84988422889&partnerID=8YFLogxK

U2 - 10.1007/s11172-015-1246-2

DO - 10.1007/s11172-015-1246-2

M3 - Article

AN - SCOPUS:84988422889

VL - 64

SP - 2908

EP - 2913

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 12

ER -

ID: 25418196