Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives

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Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives. / Zavakhina, M. S.; Samsonenko, D. G.; Dybtsev, D. N. и др.

в: Russian Chemical Bulletin, Том 64, № 12, 01.12.2015, стр. 2908-2913.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{8a99f37e020f43aabdca566fd6c9135d,

title = "Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives",

abstract = "Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.",

keywords = "chiral complexes, coordination polymers, copper, crystal structure, supramolecular interactions",

author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Argent, {S. P.} and Blake, {A. J.} and M. Schr{\"o}der and Fedin, {V. P.}",

year = "2015",

month = dec,

day = "1",

doi = "10.1007/s11172-015-1246-2",

language = "English",

volume = "64",

pages = "2908--2913",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "12",

}

RIS

TY - JOUR

T1 - Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Argent, S. P.

AU - Blake, A. J.

AU - Schröder, M.

AU - Fedin, V. P.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

AB - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

KW - chiral complexes

KW - coordination polymers

KW - copper

KW - crystal structure

KW - supramolecular interactions

UR - http://www.scopus.com/inward/record.url?scp=84988422889&partnerID=8YFLogxK

U2 - 10.1007/s11172-015-1246-2

DO - 10.1007/s11172-015-1246-2

M3 - Article

AN - SCOPUS:84988422889

VL - 64

SP - 2908

EP - 2913

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 12

ER -

ID: 25418196