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Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+). / Bryleva, Yu A.; Plyusnin, V. F.; Glinskaya, L. A. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 43, No. 3, 01.03.2017, p. 147-155.

Research output: Contribution to journal › Article › peer-review

Harvard

Bryleva, YA, Plyusnin, VF, Glinskaya, LA, Kupryakov, AS, Korol’kov, IV, Piryazev, DA & Larionov, SV 2017, 'Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+)', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 3, pp. 147-155. https://doi.org/10.1134/S1070328417020026

APA

Bryleva, Y. A., Plyusnin, V. F., Glinskaya, L. A., Kupryakov, A. S., Korol’kov, I. V., Piryazev, D. A., & Larionov, S. V. (2017). Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(3), 147-155. https://doi.org/10.1134/S1070328417020026

Vancouver

Bryleva YA, Plyusnin VF, Glinskaya LA, Kupryakov AS, Korol’kov IV, Piryazev DA et al. Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 Mar 1;43(3):147-155. doi: 10.1134/S1070328417020026

Author

Bryleva, Yu A. ; Plyusnin, V. F. ; Glinskaya, L. A. et al. / Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+). In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 ; Vol. 43, No. 3. pp. 147-155.

BibTeX

@article{2433f818d0314a7682dca0aaf9067352,
title = "Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+)",
abstract = "Complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS2 -, C4H8NCS2 -; A = NH4 +, Et4N+) are synthesized. The crystal structure of compound [Gd(Phen)(iso-Bu2PS2)3] · MeCN is determined by X-ray diffraction analysis (CIF file CCDC no. 1455418). The structure consists of molecules of the mononuclear complex [Gd(Phen)(iso-Bu2PS2)3] and MeCN. The coordination polyhedron N2S6 of the Gd atom is a distorted antiprism. The complexes exhibit phosphorescence in a range of 400–600 nm. The energies of the triplet levels of the ligands C4H8NCS2 -(23336 cm–1) and iso-Bu2PS2 -(23506 cm–1) are determined from the phosphorescence spectra of complexes (A)[Gd(L)4] in frozen ethanol (77 K).",
keywords = "1,1-dithiolate ligands, complex, gadolinium, phosphorescence, structure, PHOTOLUMINESCENCE, PHEN, MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, RARE-EARTH-METALS, LUMINESCENCE PROPERTIES, TB, DITHIOCARBAMATE COMPLEXES, ENERGY-TRANSFER, MAGNETIC-PROPERTIES",
author = "Bryleva, {Yu A.} and Plyusnin, {V. F.} and Glinskaya, {L. A.} and Kupryakov, {A. S.} and Korol{\textquoteright}kov, {I. V.} and Piryazev, {D. A.} and Larionov, {S. V.}",
year = "2017",
month = mar,
day = "1",
doi = "10.1134/S1070328417020026",
language = "English",
volume = "43",
pages = "147--155",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "3",

}

RIS

TY - JOUR

T1 - Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+)

AU - Bryleva, Yu A.

AU - Plyusnin, V. F.

AU - Glinskaya, L. A.

AU - Kupryakov, A. S.

AU - Korol’kov, I. V.

AU - Piryazev, D. A.

AU - Larionov, S. V.

PY - 2017/3/1

Y1 - 2017/3/1

N2 - Complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS2 -, C4H8NCS2 -; A = NH4 +, Et4N+) are synthesized. The crystal structure of compound [Gd(Phen)(iso-Bu2PS2)3] · MeCN is determined by X-ray diffraction analysis (CIF file CCDC no. 1455418). The structure consists of molecules of the mononuclear complex [Gd(Phen)(iso-Bu2PS2)3] and MeCN. The coordination polyhedron N2S6 of the Gd atom is a distorted antiprism. The complexes exhibit phosphorescence in a range of 400–600 nm. The energies of the triplet levels of the ligands C4H8NCS2 -(23336 cm–1) and iso-Bu2PS2 -(23506 cm–1) are determined from the phosphorescence spectra of complexes (A)[Gd(L)4] in frozen ethanol (77 K).

AB - Complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS2 -, C4H8NCS2 -; A = NH4 +, Et4N+) are synthesized. The crystal structure of compound [Gd(Phen)(iso-Bu2PS2)3] · MeCN is determined by X-ray diffraction analysis (CIF file CCDC no. 1455418). The structure consists of molecules of the mononuclear complex [Gd(Phen)(iso-Bu2PS2)3] and MeCN. The coordination polyhedron N2S6 of the Gd atom is a distorted antiprism. The complexes exhibit phosphorescence in a range of 400–600 nm. The energies of the triplet levels of the ligands C4H8NCS2 -(23336 cm–1) and iso-Bu2PS2 -(23506 cm–1) are determined from the phosphorescence spectra of complexes (A)[Gd(L)4] in frozen ethanol (77 K).

KW - 1,1-dithiolate ligands

KW - complex

KW - gadolinium

KW - phosphorescence

KW - structure

KW - PHOTOLUMINESCENCE

KW - PHEN

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURE

KW - RARE-EARTH-METALS

KW - LUMINESCENCE PROPERTIES

KW - TB

KW - DITHIOCARBAMATE COMPLEXES

KW - ENERGY-TRANSFER

KW - MAGNETIC-PROPERTIES

UR - http://www.scopus.com/inward/record.url?scp=85016059759&partnerID=8YFLogxK

U2 - 10.1134/S1070328417020026

DO - 10.1134/S1070328417020026

M3 - Article

AN - SCOPUS:85016059759

VL - 43

SP - 147

EP - 155

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 3

ER -

ID: 9048032