Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+). / Bryleva, Yu A.; Plyusnin, V. F.; Glinskaya, L. A. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 43, № 3, 01.03.2017, стр. 147-155.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+)
AU - Bryleva, Yu A.
AU - Plyusnin, V. F.
AU - Glinskaya, L. A.
AU - Kupryakov, A. S.
AU - Korol’kov, I. V.
AU - Piryazev, D. A.
AU - Larionov, S. V.
PY - 2017/3/1
Y1 - 2017/3/1
N2 - Complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS2 -, C4H8NCS2 -; A = NH4 +, Et4N+) are synthesized. The crystal structure of compound [Gd(Phen)(iso-Bu2PS2)3] · MeCN is determined by X-ray diffraction analysis (CIF file CCDC no. 1455418). The structure consists of molecules of the mononuclear complex [Gd(Phen)(iso-Bu2PS2)3] and MeCN. The coordination polyhedron N2S6 of the Gd atom is a distorted antiprism. The complexes exhibit phosphorescence in a range of 400–600 nm. The energies of the triplet levels of the ligands C4H8NCS2 -(23336 cm–1) and iso-Bu2PS2 -(23506 cm–1) are determined from the phosphorescence spectra of complexes (A)[Gd(L)4] in frozen ethanol (77 K).
AB - Complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS2 -, C4H8NCS2 -; A = NH4 +, Et4N+) are synthesized. The crystal structure of compound [Gd(Phen)(iso-Bu2PS2)3] · MeCN is determined by X-ray diffraction analysis (CIF file CCDC no. 1455418). The structure consists of molecules of the mononuclear complex [Gd(Phen)(iso-Bu2PS2)3] and MeCN. The coordination polyhedron N2S6 of the Gd atom is a distorted antiprism. The complexes exhibit phosphorescence in a range of 400–600 nm. The energies of the triplet levels of the ligands C4H8NCS2 -(23336 cm–1) and iso-Bu2PS2 -(23506 cm–1) are determined from the phosphorescence spectra of complexes (A)[Gd(L)4] in frozen ethanol (77 K).
KW - 1,1-dithiolate ligands
KW - complex
KW - gadolinium
KW - phosphorescence
KW - structure
KW - PHOTOLUMINESCENCE
KW - PHEN
KW - MOLECULAR-STRUCTURE
KW - CRYSTAL-STRUCTURE
KW - RARE-EARTH-METALS
KW - LUMINESCENCE PROPERTIES
KW - TB
KW - DITHIOCARBAMATE COMPLEXES
KW - ENERGY-TRANSFER
KW - MAGNETIC-PROPERTIES
UR - http://www.scopus.com/inward/record.url?scp=85016059759&partnerID=8YFLogxK
U2 - 10.1134/S1070328417020026
DO - 10.1134/S1070328417020026
M3 - Article
AN - SCOPUS:85016059759
VL - 43
SP - 147
EP - 155
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 3
ER -
ID: 9048032